RUcore: Rutgers University Community Repository
Chromophore shielding on metal oxide surfaces
Descriptive
TypeOfResource
Text
TitleInfo
(ID = T-1)
Title
Chromophore shielding on metal oxide surfaces
Identifier
ETD_2915
Identifier
(type = hdl)
http://hdl.rutgers.edu/1782.1/rucore10002600001.ETD.000056117
Language
LanguageTerm
(authority = ISO639-2);
(type = code)
eng
Genre
(authority = marcgt)
theses
Subject
(ID = SBJ-1);
(authority = RUETD)
Topic
Chemistry
Subject
(ID = SBJ-2);
(authority = ETD-LCSH)
Topic
Metallic oxides--Surfaces
Abstract
(type = abstract)
The work present in this thesis is divided into two parts. The common theme is the development of methods to shield chromophores on heterogeneous metal oxide surfaces; and study the effects of shielding on their surface properties.Part A describes the synthesis of homoleptic ruthenium polypyridine star-shaped complexes with conjugated oligophenylenethylene linkers on each bipyridine ligand to fix the distance between a ruthenium metal center and metal oxide surfaces in all three dimensions. Star complexes did bind covalently to the metal oxide surfaces with bidentate mode. The photophysical properties were influenced by the length of the rigid linkers. On basic TiO2 films, the injection yields decreased as the linker length increased. The injection process was on 100-150 ns time scale. Recombination rate was largely reduced (105 s-1 order) compared to the value of rigid-rods (107 s-1 order) due to well-controlled distance separation. Part B describes the aggregation study of dye@cyclodextrins on metal oxide surface. Cyclodextrins bound to TiO2 surface by –OH group. Suitable-sized cyclodextrins were found to separate pyrene and perylene derivative on ZrO2 surface. Reduced excimer band and enhanced monomer band were observed in fluorescence emission spectra.
PhysicalDescription
Form
(authority = gmd)
electronic resource
Extent
xi, 168 p. : ill.
InternetMediaType
application/pdf
InternetMediaType
text/xml
Note
(type = degree)
Ph.D.
Note
(type = bibliography)
Includes bibliographical references
Note
(type = vita)
Includes vita
Note
(type = statement of responsibility)
by Yongyi Zhang
Name
(ID = NAME-1);
(type = personal)
NamePart
(type = family)
Zhang
NamePart
(type = given)
Yongyi
NamePart
(type = date)
1980-
Role
RoleTerm
(authority = RULIB)
author
DisplayForm
Yongyi Zhang
Name
(ID = NAME-2);
(type = personal)
NamePart
(type = family)
Elena
NamePart
(type = given)
Gallopini
Role
RoleTerm
(authority = RULIB)
chair
Affiliation
Advisory Committee
DisplayForm
Gallopini Elena
Name
(ID = NAME-3);
(type = personal)
NamePart
(type = family)
He
NamePart
(type = given)
Huixin
Role
RoleTerm
(authority = RULIB)
internal member
Affiliation
Advisory Committee
DisplayForm
Huixin He
Name
(ID = NAME-4);
(type = personal)
NamePart
(type = family)
Hansen
NamePart
(type = given)
Darren
Role
RoleTerm
(authority = RULIB)
internal member
Affiliation
Advisory Committee
DisplayForm
Darren Hansen
Name
(ID = NAME-5);
(type = personal)
NamePart
(type = family)
Agrios
NamePart
(type = given)
Alexander G
Role
RoleTerm
(authority = RULIB)
outside member
Affiliation
Advisory Committee
DisplayForm
Alexander G Agrios
Name
(ID = NAME-1);
(type = corporate)
NamePart
Rutgers University
Role
RoleTerm
(authority = RULIB)
degree grantor
Name
(ID = NAME-2);
(type = corporate)
NamePart
Graduate School - Newark
Role
RoleTerm
(authority = RULIB)
school
OriginInfo
DateCreated
(qualifier = exact)
2010
DateOther
(qualifier = exact);
(type = degree)
2010-10
Place
PlaceTerm
(type = code)
xx
RelatedItem
(type = host)
TitleInfo
Title
Rutgers University Electronic Theses and Dissertations
Identifier
(type = RULIB)
ETD
RelatedItem
(type = host)
TitleInfo
Title
Graduate School - Newark Electronic Theses and Dissertations
Identifier
(type = local)
rucore10002600001
Location
PhysicalLocation
(authority = marcorg);
(displayLabel = Rutgers, The State University of New Jersey)
NjNbRU
Identifier
(type = doi)
doi:10.7282/T3TX3F5M
Genre
(authority = ExL-Esploro)
ETD doctoral
Back to the top
Rights
RightsDeclaration
(AUTHORITY = GS);
(ID = rulibRdec0006)
The author owns the copyright to this work.
Copyright
Status
Copyright protected
Availability
Status
Open
Reason
Permission or license
RightsHolder
(ID = PRH-1);
(type = personal)
Name
FamilyName
Zhang
GivenName
Yongyi
Role
Copyright Holder
RightsEvent
(ID = RE-1);
(AUTHORITY = rulib)
Type
Permission or license
DateTime
2010-09-27 14:56:46
AssociatedEntity
(ID = AE-1);
(AUTHORITY = rulib)
Role
Copyright holder
Name
Yongyi Zhang
Affiliation
Rutgers University. Graduate School - Newark
AssociatedObject
(ID = AO-1);
(AUTHORITY = rulib)
Type
License
Name
Author Agreement License
Detail
I hereby grant to the Rutgers University Libraries and to my school the non-exclusive right to archive, reproduce and distribute my thesis or dissertation, in whole or in part, and/or my abstract, in whole or in part, in and from an electronic format, subject to the release date subsequently stipulated in this submittal form and approved by my school. I represent and stipulate that the thesis or dissertation and its abstract are my original work, that they do not infringe or violate any rights of others, and that I make these grants as the sole owner of the rights to my thesis or dissertation and its abstract. I represent that I have obtained written permissions, when necessary, from the owner(s) of each third party copyrighted matter to be included in my thesis or dissertation and will supply copies of such upon request by my school. I acknowledge that RU ETD and my school will not distribute my thesis or dissertation or its abstract if, in their reasonable judgment, they believe all such rights have not been secured. I acknowledge that I retain ownership rights to the copyright of my work. I also retain the right to use all or part of this thesis or dissertation in future works, such as articles or books.
Back to the top
Technical
ContentModel
ETD
MimeType
(TYPE = file)
application/pdf
MimeType
(TYPE = container)
application/x-tar
FileSize
(UNIT = bytes)
6041600
Checksum
(METHOD = SHA1)
a7ae8f526d7843756b4172ffca1c879c970cf7b6
Back to the top
Statistical Profile