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New reactions, mechanisms, and stereochemical theory in organic chemistry

Descriptive

TypeOfResource
Text
TitleInfo (ID = T-1)
Title
New reactions, mechanisms, and stereochemical theory in organic chemistry
Identifier
ETD_2885
Identifier (type = hdl)
http://hdl.rutgers.edu/1782.1/rucore10001600001.ETD.000056477
Language
LanguageTerm (authority = ISO639-2); (type = code)
eng
Genre (authority = marcgt)
theses
Subject (ID = SBJ-1); (authority = RUETD)
Topic
Chemistry and Chemical Biology
Subject (ID = SBJ-2); (authority = ETD-LCSH)
Topic
Chemistry, Organic
Subject (ID = SBJ-3); (authority = ETD-LCSH)
Topic
Stereochemistry
Subject (ID = SBJ-4); (authority = ETD-LCSH)
Topic
Allene
Abstract (type = abstract)
Here we describe a new method for the formation of allenes utilizing a Grob-like fragmentation along with a mechanistic study. The mechanism of the azide and thio acid amidation is presented. This mechanism was found to go through a thiatriazoline, and the reaction was successfully extended to the isoelectronic coupling of dithio acids with azides to form thioamide. Finally, distortional asymmetry is presented as new model for understanding stereoselectivity in sterically unbiased systems. This model deomonstrates that small ground state perturbations can lead to significant energy differences between diastereomeric tranistion states.
PhysicalDescription
Form (authority = gmd)
electronic resource
Extent
vii, 254 p. : ill.
InternetMediaType
application/pdf
InternetMediaType
text/xml
Note (type = degree)
Ph.D.
Note (type = bibliography)
Includes bibliographical references
Note (type = vita)
Includes vita
Note (type = statement of responsibility)
by Robert Vincent Kolakowski
Name (ID = NAME-1); (type = personal)
NamePart (type = family)
Kolakowski
NamePart (type = given)
Robert Vincent
NamePart (type = date)
1976-
Role
RoleTerm (authority = RULIB)
author
DisplayForm
Robert Kolakowski
Name (ID = NAME-2); (type = personal)
NamePart (type = family)
Williams
NamePart (type = given)
Lawrence J
Role
RoleTerm (authority = RULIB)
chair
Affiliation
Advisory Committee
DisplayForm
Lawrence J Williams
Name (ID = NAME-3); (type = personal)
NamePart (type = family)
Knapp
NamePart (type = given)
Spencer
Role
RoleTerm (authority = RULIB)
internal member
Affiliation
Advisory Committee
DisplayForm
Spencer Knapp
Name (ID = NAME-4); (type = personal)
NamePart (type = family)
Seidel
NamePart (type = given)
Daniel
Role
RoleTerm (authority = RULIB)
internal member
Affiliation
Advisory Committee
DisplayForm
Daniel Seidel
Name (ID = NAME-5); (type = personal)
NamePart (type = family)
Shaw
NamePart (type = given)
Scott
Role
RoleTerm (authority = RULIB)
outside member
Affiliation
Advisory Committee
DisplayForm
Scott Shaw
Name (ID = NAME-1); (type = corporate)
NamePart
Rutgers University
Role
RoleTerm (authority = RULIB)
degree grantor
Name (ID = NAME-2); (type = corporate)
NamePart
Graduate School - New Brunswick
Role
RoleTerm (authority = RULIB)
school
OriginInfo
DateCreated (qualifier = exact)
2010
DateOther (qualifier = exact); (type = degree)
2010-10
Place
PlaceTerm (type = code)
xx
RelatedItem (type = host)
TitleInfo
Title
Rutgers University Electronic Theses and Dissertations
Identifier (type = RULIB)
ETD
RelatedItem (type = host)
TitleInfo
Title
Graduate School - New Brunswick Electronic Theses and Dissertations
Identifier (type = local)
rucore19991600001
Location
PhysicalLocation (authority = marcorg); (displayLabel = Rutgers, The State University of New Jersey)
NjNbRU
Identifier (type = doi)
doi:10.7282/T3V40TZQ
Genre (authority = ExL-Esploro)
ETD doctoral
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Rights

RightsDeclaration (AUTHORITY = GS); (ID = rulibRdec0006)
The author owns the copyright to this work.
Copyright
Status
Copyright protected
Availability
Status
Open
Reason
Permission or license
RightsHolder (ID = PRH-1); (type = personal)
Name
FamilyName
Kolakowski
GivenName
Robert
Role
Copyright Holder
RightsEvent (ID = RE-1); (AUTHORITY = rulib)
Type
Permission or license
DateTime
2010-09-20 22:21:44
AssociatedEntity (ID = AE-1); (AUTHORITY = rulib)
Role
Copyright holder
Name
Robert Kolakowski
Affiliation
Rutgers University. Graduate School - New Brunswick
AssociatedObject (ID = AO-1); (AUTHORITY = rulib)
Type
License
Name
Author Agreement License
Detail
I hereby grant to the Rutgers University Libraries and to my school the non-exclusive right to archive, reproduce and distribute my thesis or dissertation, in whole or in part, and/or my abstract, in whole or in part, in and from an electronic format, subject to the release date subsequently stipulated in this submittal form and approved by my school. I represent and stipulate that the thesis or dissertation and its abstract are my original work, that they do not infringe or violate any rights of others, and that I make these grants as the sole owner of the rights to my thesis or dissertation and its abstract. I represent that I have obtained written permissions, when necessary, from the owner(s) of each third party copyrighted matter to be included in my thesis or dissertation and will supply copies of such upon request by my school. I acknowledge that RU ETD and my school will not distribute my thesis or dissertation or its abstract if, in their reasonable judgment, they believe all such rights have not been secured. I acknowledge that I retain ownership rights to the copyright of my work. I also retain the right to use all or part of this thesis or dissertation in future works, such as articles or books.
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Technical

ContentModel
ETD
MimeType (TYPE = file)
application/pdf
MimeType (TYPE = container)
application/x-tar
FileSize (UNIT = bytes)
28221440
Checksum (METHOD = SHA1)
235eb754fba19aa0a4d45aae374b37c693e2f15c
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