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Development of catalytic enantioselective Aldol, Mannich, Friedlaender reactions
Descriptive
TypeOfResource
Text
TitleInfo
(ID = T-1)
Title
Development of catalytic enantioselective Aldol, Mannich, Friedlaender reactions
Identifier
ETD_2964
Identifier
(type = hdl)
http://hdl.rutgers.edu/1782.1/rucore10001600001.ETD.000056483
Language
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(type = code)
eng
Genre
(authority = marcgt)
theses
Subject
(ID = SBJ-1);
(authority = RUETD)
Topic
Chemistry and Chemical Biology
Subject
(ID = SBJ-2);
(authority = ETD-LCSH)
Topic
Enantioselective catalysis
Subject
(ID = SBJ-3);
(authority = ETD-LCSH)
Topic
Diamino amino acids
Abstract
(type = abstract)
In Chapter I, I introduce the explosive development of enantioselective organocatalysis. Selected significant landmarks in this area are reviewed and highlighted in this chapter. Chapter II focuses on the development of catalytic enantioselective aldol additions of α-isothiocyanato imides to aldehydes and α-ketoesters. Chapter III outlines the development of enantioselective Mannich reactions of α-isothiocyanato imides with activated imines and the asymmetric synthesis of α, β-diamino acid derivatives. In Chapter IV, the first catalytic enantioselective Friedländer condensation is described which provides access to quinolines and tacrines with remote stereogenic centers.
PhysicalDescription
Form
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electronic resource
Extent
xiv, 469 p. : ill.
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application/pdf
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text/xml
Note
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Ph.D.
Note
(type = bibliography)
Includes bibliographical references
Note
(type = vita)
Includes vita
Note
(type = statement of responsibility)
by Le Li
Name
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Li
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Le
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1980-
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author
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Le Li
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Seidel
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Daniel
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chair
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Advisory Committee
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Daniel Seidel
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Hultzsch
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Kai
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internal member
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Advisory Committee
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Kai Hultzsch
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(ID = NAME-4);
(type = personal)
NamePart
(type = family)
Zhang
NamePart
(type = given)
Xumu
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(authority = RULIB)
internal member
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Advisory Committee
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Xumu Zhang
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(ID = NAME-5);
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NamePart
(type = family)
Zhang
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(type = given)
Haiming
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outside member
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Advisory Committee
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Haiming Zhang
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NamePart
Rutgers University
Role
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degree grantor
Name
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NamePart
Graduate School - New Brunswick
Role
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school
OriginInfo
DateCreated
(qualifier = exact)
2010
DateOther
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(type = degree)
2010
Place
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(type = code)
xx
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TitleInfo
Title
Rutgers University Electronic Theses and Dissertations
Identifier
(type = RULIB)
ETD
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(type = host)
TitleInfo
Title
Graduate School - New Brunswick Electronic Theses and Dissertations
Identifier
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rucore19991600001
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NjNbRU
Identifier
(type = doi)
doi:10.7282/T3GT5MX5
Genre
(authority = ExL-Esploro)
ETD doctoral
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Rights
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The author owns the copyright to this work.
Copyright
Status
Copyright protected
Availability
Status
Open
Reason
Permission or license
RightsHolder
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(type = personal)
Name
FamilyName
Li
GivenName
Le
Role
Copyright Holder
RightsEvent
(ID = RE-1);
(AUTHORITY = rulib)
Type
Permission or license
DateTime
2010-09-30 13:24:12
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Name
Le Li
Affiliation
Rutgers University. Graduate School - New Brunswick
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License
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Author Agreement License
Detail
I hereby grant to the Rutgers University Libraries and to my school the non-exclusive right to archive, reproduce and distribute my thesis or dissertation, in whole or in part, and/or my abstract, in whole or in part, in and from an electronic format, subject to the release date subsequently stipulated in this submittal form and approved by my school. I represent and stipulate that the thesis or dissertation and its abstract are my original work, that they do not infringe or violate any rights of others, and that I make these grants as the sole owner of the rights to my thesis or dissertation and its abstract. I represent that I have obtained written permissions, when necessary, from the owner(s) of each third party copyrighted matter to be included in my thesis or dissertation and will supply copies of such upon request by my school. I acknowledge that RU ETD and my school will not distribute my thesis or dissertation or its abstract if, in their reasonable judgment, they believe all such rights have not been secured. I acknowledge that I retain ownership rights to the copyright of my work. I also retain the right to use all or part of this thesis or dissertation in future works, such as articles or books.
RightsEvent
(ID = RE-2);
(AUTHORITY = rulib)
Type
Embargo
DateTime
2010-10-31
Detail
Access to this PDF has been restricted at the author's request. It will be publicly available after October 31st, 2011.
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ETD
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application/pdf
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application/x-tar
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15790080
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