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Study of hydrogen bonding interactions via x-ray analysis
Descriptive
TitleInfo
Title
Study of hydrogen bonding interactions via x-ray analysis
Name
(type = personal)
NamePart
(type = family)
Gorlova
NamePart
(type = given)
Olga
NamePart
(type = date)
1990-
DisplayForm
Olga Gorlova
Role
RoleTerm
(authority = RULIB)
author
Name
(type = personal)
NamePart
(type = family)
Sheridan
NamePart
(type = given)
John B.
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John B. Sheridan
Affiliation
Advisory Committee
Role
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chair
Name
(type = personal)
NamePart
(type = family)
Lalancette
NamePart
(type = given)
Roger A.
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Roger A. Lalancette
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Advisory Committee
Role
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(authority = RULIB)
internal member
Name
(type = personal)
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(type = family)
Schlegel
NamePart
(type = given)
James
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James Schlegel
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Advisory Committee
Role
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(authority = RULIB)
internal member
Name
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NamePart
(type = family)
Mendelsohn
NamePart
(type = given)
Richard
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Richard Mendelsohn
Affiliation
Advisory Committee
Role
RoleTerm
(authority = RULIB)
internal member
Name
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NamePart
Rutgers University
Role
RoleTerm
(authority = RULIB)
degree grantor
Name
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NamePart
Graduate School - Newark
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school
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Text
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theses
OriginInfo
DateCreated
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2012
DateOther
(qualifier = exact);
(type = degree)
2012-05
CopyrightDate
(qualifier = exact)
2012
Place
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(type = code)
xx
Language
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(authority = ISO639-2b);
(type = code)
eng
Abstract
(type = abstract)
X-ray diffraction is a useful method for studying the absolute structure of a molecule or complex in crystalline form. Analysis and determination by this technique provides information on atomic positions within the molecule as well as bond lengths, angles, unit cell, space group and symmetry. We used X-ray analysis to study hydrogen-bonding interactions in a number of molecules. A hydrogen bond occurs between a hydrogen atom covalently bonded to a first row electronegative atom and weakly bonded to another first-row electronegative atom having at least one lone pair of electrons. Hydrogen-bonding interactions affect the coordination and complexation of molecular compounds. In this paper, we examine a structural anomaly of a far-too-short hydrogen bond in H5O2+cation and describe the various methods employed to resolve this issue. We also investigate intra- and inter-molecular hydrogen bonding in an oligosaccharide, as well as sulfate ion coordination due to hydrogen bonding in two different macrocycles.
Subject
(authority = RUETD)
Topic
Chemistry
Subject
(authority = ETD-LCSH)
Topic
Hydrogen bonding
RelatedItem
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TitleInfo
Title
Rutgers University Electronic Theses and Dissertations
Identifier
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ETD
Identifier
ETD_4073
PhysicalDescription
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electronic resource
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application/pdf
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text/xml
Extent
viii, 98 p. : ill.
Note
(type = degree)
M.S.
Note
(type = bibliography)
Includes bibliographical references
Note
(type = vita)
Includes vita
Note
(type = statement of responsibility)
by Olga Gorlova
Subject
(authority = ETD-LCSH)
Topic
X-rays--Diffraction
Identifier
(type = hdl)
http://hdl.rutgers.edu/1782.1/rucore10002600001.ETD.000065034
RelatedItem
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TitleInfo
Title
Graduate School - Newark Electronic Theses and Dissertations
Identifier
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rucore10002600001
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NjNbRU
Identifier
(type = doi)
doi:10.7282/T3HT2N87
Genre
(authority = ExL-Esploro)
ETD graduate
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Rights
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The author owns the copyright to this work.
RightsHolder
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Name
FamilyName
Gorlova
GivenName
Olga
Role
Copyright Holder
RightsEvent
Type
Permission or license
DateTime
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(point = start);
(qualifier = exact)
2012-05-01 13:08:16
AssociatedEntity
Name
Olga Gorlova
Role
Copyright holder
Affiliation
Rutgers University. Graduate School - Newark
AssociatedObject
Type
License
Name
Author Agreement License
Detail
I hereby grant to the Rutgers University Libraries and to my school the non-exclusive right to archive, reproduce and distribute my thesis or dissertation, in whole or in part, and/or my abstract, in whole or in part, in and from an electronic format, subject to the release date subsequently stipulated in this submittal form and approved by my school. I represent and stipulate that the thesis or dissertation and its abstract are my original work, that they do not infringe or violate any rights of others, and that I make these grants as the sole owner of the rights to my thesis or dissertation and its abstract. I represent that I have obtained written permissions, when necessary, from the owner(s) of each third party copyrighted matter to be included in my thesis or dissertation and will supply copies of such upon request by my school. I acknowledge that RU ETD and my school will not distribute my thesis or dissertation or its abstract if, in their reasonable judgment, they believe all such rights have not been secured. I acknowledge that I retain ownership rights to the copyright of my work. I also retain the right to use all or part of this thesis or dissertation in future works, such as articles or books.
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DateTime
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2012-08-08
DateTime
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2013-05-31
Detail
Access to this PDF has been restricted at the author's request. It will be publicly available after May 31, 2013.
Copyright
Status
Copyright protected
Availability
Status
Open
Reason
Permission or license
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2024448
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