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Physical chemistry of ionic liquids
Descriptive
TitleInfo
Title
Physical chemistry of ionic liquids
SubTitle
structure and photochemical reactions
Name
(type = personal)
NamePart
(type = family)
Lee
NamePart
(type = given)
Heather Yoonsoo
DisplayForm
Heather Lee
Role
RoleTerm
(authority = RULIB)
author
Name
(type = personal)
NamePart
(type = family)
Castner, Jr.
NamePart
(type = given)
Edward W
DisplayForm
Edward W Castner, Jr.
Affiliation
Advisory Committee
Role
RoleTerm
(authority = RULIB)
chair
Name
(type = personal)
NamePart
(type = family)
Greenblatt
NamePart
(type = given)
Martha
DisplayForm
Martha Greenblatt
Affiliation
Advisory Committee
Role
RoleTerm
(authority = RULIB)
internal member
Name
(type = personal)
NamePart
(type = family)
Case
NamePart
(type = given)
Dave
DisplayForm
Dave Case
Affiliation
Advisory Committee
Role
RoleTerm
(authority = RULIB)
internal member
Name
(type = personal)
NamePart
(type = family)
Wishart
NamePart
(type = given)
James F
DisplayForm
James F Wishart
Affiliation
Advisory Committee
Role
RoleTerm
(authority = RULIB)
outside member
Name
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NamePart
Rutgers University
Role
RoleTerm
(authority = RULIB)
degree grantor
Name
(type = corporate)
NamePart
Graduate School - New Brunswick
Role
RoleTerm
(authority = RULIB)
school
TypeOfResource
Text
Genre
(authority = marcgt)
theses
OriginInfo
DateCreated
(qualifier = exact)
2012
DateOther
(qualifier = exact);
(type = degree)
2012-10
Place
PlaceTerm
(type = code)
xx
Language
LanguageTerm
(authority = ISO639-2b);
(type = code)
eng
Abstract
(type = abstract)
Physical chemistry of ionic liquids (ILs) is investigated. First, ILs are used as solvents for photoinduced intramolecular electron-transfer (ET) reactions of a donor-bridge- acceptor compound. The solvation dynamic effect of the ILs on the intramolecular ET is compared with that in neutral solvents. The ET rates in ionic liquids are slower and very broadly distributed compared to narrowly distributed rates in the neutral solvents. In addition, the reaction kinetics in the ILs are dynamically heterogeneous. Dynamic heterogeneity, however, is not a unique quality to ILs; glass systems also show such behavior. To determine the degree to which this dynamic heterogeneity arises from, we examine the structural heterogeneity of ILs. We study the local structure of ILs using 2D NMR spectroscopy on the set of four homologous ILs. The results suggest intermolecular interactions between hydrogen atoms on the cation ether- chains and the fluorine atoms on the anions - such interaction is not found for the octyl-chained ILs. Lastly, physical and chemical properties of novel paramagnetic ionic liquids/solids are characterized. The crystal structures of these ionic compounds are solved and the magnetic properties are reported.
Subject
(authority = RUETD)
Topic
Chemistry and Chemical Biology
RelatedItem
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TitleInfo
Title
Rutgers University Electronic Theses and Dissertations
Identifier
(type = RULIB)
ETD
Identifier
ETD_4368
PhysicalDescription
Form
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electronic resource
InternetMediaType
application/pdf
InternetMediaType
text/xml
Extent
xx, 154 p. : ill.
Note
(type = degree)
Ph.D.
Note
(type = bibliography)
Includes bibliographical references
Note
(type = statement of responsibility)
by Heather Yoonsoo Lee
Subject
(authority = ETD-LCSH)
Topic
Ionic solutions
Subject
(authority = ETD-LCSH)
Topic
Liquids
Subject
(authority = ETD-LCSH)
Topic
Chemistry, Physical and theoretical
Identifier
(type = hdl)
http://hdl.rutgers.edu/1782.1/rucore10001600001.ETD.000066889
RelatedItem
(type = host)
TitleInfo
Title
Graduate School - New Brunswick Electronic Theses and Dissertations
Identifier
(type = local)
rucore19991600001
Location
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(authority = marcorg);
(displayLabel = Rutgers, The State University of New Jersey)
NjNbRU
Identifier
(type = doi)
doi:10.7282/T3Q52NDB
Genre
(authority = ExL-Esploro)
ETD doctoral
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Rights
RightsDeclaration
(ID = rulibRdec0006)
The author owns the copyright to this work.
RightsHolder
(type = personal)
Name
FamilyName
Lee
GivenName
Heather
Role
Copyright Holder
RightsEvent
Type
Permission or license
DateTime
(encoding = w3cdtf);
(qualifier = exact);
(point = start)
2012-10-03 13:07:32
AssociatedEntity
Name
Heather Lee
Role
Copyright holder
Affiliation
Rutgers University. Graduate School - New Brunswick
AssociatedObject
Type
License
Name
Author Agreement License
Detail
I hereby grant to the Rutgers University Libraries and to my school the non-exclusive right to archive, reproduce and distribute my thesis or dissertation, in whole or in part, and/or my abstract, in whole or in part, in and from an electronic format, subject to the release date subsequently stipulated in this submittal form and approved by my school. I represent and stipulate that the thesis or dissertation and its abstract are my original work, that they do not infringe or violate any rights of others, and that I make these grants as the sole owner of the rights to my thesis or dissertation and its abstract. I represent that I have obtained written permissions, when necessary, from the owner(s) of each third party copyrighted matter to be included in my thesis or dissertation and will supply copies of such upon request by my school. I acknowledge that RU ETD and my school will not distribute my thesis or dissertation or its abstract if, in their reasonable judgment, they believe all such rights have not been secured. I acknowledge that I retain ownership rights to the copyright of my work. I also retain the right to use all or part of this thesis or dissertation in future works, such as articles or books.
Copyright
Status
Copyright protected
Availability
Status
Open
Reason
Permission or license
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Technical
FileSize
(UNIT = bytes)
7370752
OperatingSystem
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windows xp
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application/pdf
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application/x-tar
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7372800
Checksum
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