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Unambiguous full multinuclear NMR assignment of 4-amino-1,1,2,2,9,9,10,10-octafluoro[2.2]paracycylophane & NMR differentiation of its enantiomers, and related compounds
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Rabinowitz, Sheryl. Unambiguous full multinuclear NMR assignment of 4-amino-1,1,2,2,9,9,10,10-octafluoro[2.2]paracycylophane & NMR differentiation of its enantiomers, and related compounds. Retrieved from https://doi.org/doi:10.7282/T3B56HGP

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TitleUnambiguous full multinuclear NMR assignment of 4-amino-1,1,2,2,9,9,10,10-octafluoro[2.2]paracycylophane & NMR differentiation of its enantiomers, and related compounds
NameRabinowitz, Sheryl (author); Roche, Alex J (chair); Kumi, George A (internal member); Canturk, Belgin (outside member); Rutgers University; Camden Graduate School
Date Created2013
Other Date2013-01 (degree)
SubjectChemistry, Nuclear magnetic resonance, Chirality, Cyclophanes
Extentxii, 127 p. : ill.
DescriptionFor the first time the full multinuclear ¹H, ¹³C, and ¹⁹F assignments were established for 4-amino-1,1,2,2,9,9,10,10-octafluoro[2.2]paracyclophane (OFP-NH2). These were achieved by using a combination of 1D, COSY, and HETCOR NMR techniques. The assignments were later confirmed by nOe experiments. The interaction of OFP-NH₂ with different chiral shift reagents was explored, and it was shown that it is possible to clearly detect both enantiomers of the planar chiral OFP-NH₂ (in both the ¹H and ¹⁹F NMR). This method of chiral discrimination was also shown to be applicable to other similar chiral OFP derivatives.
NoteM.S.
NoteIncludes bibliographical references
Noteby Sheryl Rabinowitz
Genretheses, ETD graduate
Persistent URLhttps://doi.org/doi:10.7282/T3B56HGP
Languageeng
CollectionCamden Graduate School Electronic Theses and Dissertations
Organization NameRutgers, The State University of New Jersey
RightsThe author owns the copyright to this work.
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