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Adsorption of aromatic sulfur compounds on metal-organic frameworks (MOFs)
Descriptive
TitleInfo
Title
Adsorption of aromatic sulfur compounds on metal-organic frameworks (MOFs)
Name
(type = personal)
NamePart
(type = family)
Demir
NamePart
(type = given)
Muslum
NamePart
(type = date)
1987-
DisplayForm
muslum demir
Role
RoleTerm
(authority = RULIB)
author
Name
(type = personal)
NamePart
(type = family)
Samokhvalov
NamePart
(type = given)
Alexander
DisplayForm
Alexander Samokhvalov
Affiliation
Advisory Committee
Role
RoleTerm
(authority = RULIB)
chair
Name
(type = personal)
NamePart
(type = family)
Roche
NamePart
(type = given)
Alex J.
DisplayForm
Alex J. Roche
Affiliation
Advisory Committee
Role
RoleTerm
(authority = RULIB)
co-chair
Name
(type = personal)
NamePart
(type = family)
Kumi
NamePart
(type = given)
George
DisplayForm
George Kumi
Affiliation
Advisory Committee
Role
RoleTerm
(authority = RULIB)
co-chair
Name
(type = corporate)
NamePart
Rutgers University
Role
RoleTerm
(authority = RULIB)
degree grantor
Name
(type = corporate)
NamePart
Camden Graduate School
Role
RoleTerm
(authority = RULIB)
school
TypeOfResource
Text
Genre
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theses
OriginInfo
DateCreated
(qualifier = exact)
2013
DateOther
(qualifier = exact);
(type = degree)
2013-05
Place
PlaceTerm
(type = code)
xx
Language
LanguageTerm
(authority = ISO639-2b);
(type = code)
eng
Abstract
(type = abstract)
Large-ring aromatic sulfur compounds, e.g., benzothiophene (BT), dibenzothiophene (DBT), present in petroleum and liquid fuels are harmful to human health and the environment. These compounds cause acid rain due to SO2 formation upon combustion of liquid fossil fuels. We studied the use of Metal Organic Frameworks (MOFs), e.g., Cu-MOF Basolite C300, to remove aromatic sulfur compounds from model liquid fossil fuels selective way and in a non-destructive fashion. The kinetics of adsorption of aromatic sulfur compounds on Cupper-MOF (Cu-MOF) was investigated under ambient conditions. The adsorption capacity of Cu-MOF with respect to large-ring aromatic sulfur compounds was examined under thermodynamic equilibrium at different temperatures. The chemical analysis of the liquid phase was performed by UV/VIS spectroscopy (quantitative determination) and high performance liquid chromatography HPLC (qualitative chemical analysis). Quantum chemical simulations of the structure of the aromatic sulfur compound DBT and its molecular spectra were conducted. Evidence of molecular interaction between MOFs and aromatic sulfur compounds was shown by fluorescence spectroscopy.
Subject
(authority = RUETD)
Topic
Chemistry
RelatedItem
(type = host)
TitleInfo
Title
Rutgers University Electronic Theses and Dissertations
Identifier
(type = RULIB)
ETD
Identifier
ETD_4750
PhysicalDescription
Form
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electronic resource
InternetMediaType
application/pdf
InternetMediaType
text/xml
Note
Supplementary File: Supplementary File
Extent
viii, 52 p. : ill.
Note
(type = degree)
M.S.
Note
(type = bibliography)
Includes bibliographical references
Note
(type = statement of responsibility)
by Muslum Demir
Subject
(authority = ETD-LCSH)
Topic
Metal organic chemical vapor deposition
Subject
(authority = ETD-LCSH)
Topic
Sulfur compounds--Physiological effect
Subject
(authority = ETD-LCSH)
Topic
Sulfur compounds--Absorption and adsorption
Identifier
(type = hdl)
http://hdl.rutgers.edu/1782.1/rucore10005600001.ETD.000068565
RelatedItem
(type = host)
TitleInfo
Title
Camden Graduate School Electronic Theses and Dissertations
Identifier
(type = local)
rucore10005600001
Location
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(displayLabel = Rutgers, The State University of New Jersey)
NjNbRU
Identifier
(type = doi)
doi:10.7282/T3Z31X8Z
Genre
(authority = ExL-Esploro)
ETD graduate
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Rights
RightsDeclaration
(ID = rulibRdec0006)
The author owns the copyright to this work.
RightsHolder
(type = personal)
Name
FamilyName
demir
GivenName
muslum
Role
Copyright Holder
RightsEvent
Type
Permission or license
DateTime
(encoding = w3cdtf);
(qualifier = exact);
(point = start)
2013-05-01 00:54:22
AssociatedEntity
Name
muslum demir
Role
Copyright holder
Affiliation
Rutgers University. Camden Graduate School
AssociatedObject
Type
License
Name
Author Agreement License
Detail
I hereby grant to the Rutgers University Libraries and to my school the non-exclusive right to archive, reproduce and distribute my thesis or dissertation, in whole or in part, and/or my abstract, in whole or in part, in and from an electronic format, subject to the release date subsequently stipulated in this submittal form and approved by my school. I represent and stipulate that the thesis or dissertation and its abstract are my original work, that they do not infringe or violate any rights of others, and that I make these grants as the sole owner of the rights to my thesis or dissertation and its abstract. I represent that I have obtained written permissions, when necessary, from the owner(s) of each third party copyrighted matter to be included in my thesis or dissertation and will supply copies of such upon request by my school. I acknowledge that RU ETD and my school will not distribute my thesis or dissertation or its abstract if, in their reasonable judgment, they believe all such rights have not been secured. I acknowledge that I retain ownership rights to the copyright of my work. I also retain the right to use all or part of this thesis or dissertation in future works, such as articles or books.
RightsEvent
DateTime
(encoding = w3cdtf);
(qualifier = exact);
(point = start)
2013-05-31
DateTime
(encoding = w3cdtf);
(qualifier = exact);
(point = end)
2015-05-31
Type
Embargo
Detail
Access to this PDF has been restricted at the author's request. It will be publicly available after May 31st, 2015.
Copyright
Status
Copyright protected
Availability
Status
Open
Reason
Permission or license
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Technical
RULTechMD
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ContentModel
ETD
OperatingSystem
(VERSION = 5.1)
windows xp
RULTechMD
(ID = TECHNICAL2)
ContentModel
ETD
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