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Architectural influence of FeF₂ films on electrochemical failure modes
Descriptive
TitleInfo
Title
Architectural influence of FeF₂ films on electrochemical failure modes
Name
(type = personal)
NamePart
(type = family)
Parkinson
NamePart
(type = given)
Matthew Frank
NamePart
(type = date)
1974-
DisplayForm
Matthew Parkinson
Role
RoleTerm
(authority = RULIB)
author
Name
(type = personal)
NamePart
(type = family)
Amatucci
NamePart
(type = given)
Glenn
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Glenn Amatucci
Affiliation
Advisory Committee
Role
RoleTerm
(authority = RULIB)
chair
Name
(type = personal)
NamePart
(type = family)
Klein
NamePart
(type = given)
Lisa
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Lisa Klein
Affiliation
Advisory Committee
Role
RoleTerm
(authority = RULIB)
internal member
Name
(type = personal)
NamePart
(type = family)
Safari
NamePart
(type = given)
Ahmad
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Ahmad Safari
Affiliation
Advisory Committee
Role
RoleTerm
(authority = RULIB)
internal member
Name
(type = personal)
NamePart
(type = family)
Cook-Chennault
NamePart
(type = given)
Kimberly
DisplayForm
Kimberly Cook-Chennault
Affiliation
Advisory Committee
Role
RoleTerm
(authority = RULIB)
outside member
Name
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NamePart
Rutgers University
Role
RoleTerm
(authority = RULIB)
degree grantor
Name
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NamePart
Graduate School - New Brunswick
Role
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(authority = RULIB)
school
TypeOfResource
Text
Genre
(authority = marcgt)
theses
OriginInfo
DateCreated
(qualifier = exact)
2013
DateOther
(qualifier = exact);
(type = degree)
2013-05
Place
PlaceTerm
(type = code)
xx
Language
LanguageTerm
(authority = ISO639-2b);
(type = code)
eng
Abstract
(type = abstract)
Iron fluoride (FeF2) is an attractive material for use as nanocomposite conversion reaction based cathodes in lithium ion batteries because of its high specific theoretical capacity of 571mAh/g. However, despite the optimistic potential of FeF2 to advance battery cathodes, the cycling performance of the material requires further development for it to be a viable cathode candidate. A deeper understanding is required of how orientation, selective reaction fronts, and morphology impact the electrochemical performance. FeF2 films of various degrees of vertical porosity and thickness were fabricated through the use of dynamic glancing angle deposition. Respectable performance was obtained with film thicknesses of 850nm, well above the nanodimensions typically required to trigger electrochemical activity. The structure – electrochemical property relationships were used to formulate insights on the electronic and ionic transport limitations seen in typical nanocomposite powders
Subject
(authority = RUETD)
Topic
Materials Science and Engineering
RelatedItem
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TitleInfo
Title
Rutgers University Electronic Theses and Dissertations
Identifier
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ETD
Identifier
ETD_4599
PhysicalDescription
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electronic resource
InternetMediaType
application/pdf
InternetMediaType
text/xml
Extent
xiv, 165 p. : ill.
Note
(type = degree)
Ph.D.
Note
(type = bibliography)
Includes bibliographical references
Note
(type = vita)
Includes vita
Note
(type = statement of responsibility)
by Matthew Frank Parkinson
Subject
(authority = ETD-LCSH)
Topic
Lithium ion batteries
Subject
(authority = ETD-LCSH)
Topic
Cathodes
Subject
(authority = ETD-LCSH)
Topic
Nanocomposites (Materials)
Identifier
(type = hdl)
http://hdl.rutgers.edu/1782.1/rucore10001600001.ETD.000068932
RelatedItem
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TitleInfo
Title
Graduate School - New Brunswick Electronic Theses and Dissertations
Identifier
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rucore19991600001
Location
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(displayLabel = Rutgers, The State University of New Jersey)
NjNbRU
Identifier
(type = doi)
doi:10.7282/T3D21W6B
Genre
(authority = ExL-Esploro)
ETD doctoral
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Rights
RightsDeclaration
(ID = rulibRdec0006)
The author owns the copyright to this work.
RightsHolder
(type = personal)
Name
FamilyName
Parkinson
GivenName
Matthew
Role
Copyright Holder
RightsEvent
Type
Permission or license
DateTime
(encoding = w3cdtf);
(qualifier = exact);
(point = start)
2013-04-08 16:06:22
AssociatedEntity
Name
Matthew Parkinson
Role
Copyright holder
Affiliation
Rutgers University. Graduate School - New Brunswick
AssociatedObject
Type
License
Name
Author Agreement License
Detail
I hereby grant to the Rutgers University Libraries and to my school the non-exclusive right to archive, reproduce and distribute my thesis or dissertation, in whole or in part, and/or my abstract, in whole or in part, in and from an electronic format, subject to the release date subsequently stipulated in this submittal form and approved by my school. I represent and stipulate that the thesis or dissertation and its abstract are my original work, that they do not infringe or violate any rights of others, and that I make these grants as the sole owner of the rights to my thesis or dissertation and its abstract. I represent that I have obtained written permissions, when necessary, from the owner(s) of each third party copyrighted matter to be included in my thesis or dissertation and will supply copies of such upon request by my school. I acknowledge that RU ETD and my school will not distribute my thesis or dissertation or its abstract if, in their reasonable judgment, they believe all such rights have not been secured. I acknowledge that I retain ownership rights to the copyright of my work. I also retain the right to use all or part of this thesis or dissertation in future works, such as articles or books.
Copyright
Status
Copyright protected
Availability
Status
Open
Reason
Permission or license
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Technical
RULTechMD
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ContentModel
ETD
OperatingSystem
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windows xp
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