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Using electrical chemical impedance spectroscopy to determine nanocapillary geometry and differential capacitance by developing a variable topology network circuit model
Descriptive
TitleInfo
Title
Using electrical chemical impedance spectroscopy to determine nanocapillary geometry and differential capacitance by developing a variable topology network circuit model
Name
(type = personal)
NamePart
(type = family)
Vitarelli
NamePart
(type = given)
Michael J.
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Michael Vitarelli
Role
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(authority = RULIB)
author
Name
(type = personal)
NamePart
(type = family)
Talaga
NamePart
(type = given)
David S
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David S Talaga
Affiliation
Advisory Committee
Role
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(authority = RULIB)
chair
Name
(type = personal)
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(type = family)
Castner
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(type = given)
Edward W
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Edward W Castner
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Advisory Committee
Role
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internal member
Name
(type = personal)
NamePart
(type = family)
Hinch
NamePart
(type = given)
Barbara J
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Barbara J Hinch
Affiliation
Advisory Committee
Role
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internal member
Name
(type = personal)
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(type = family)
Nemark
NamePart
(type = given)
Alexander
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Alexander Nemark
Affiliation
Advisory Committee
Role
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(authority = RULIB)
outside member
Name
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NamePart
Rutgers University
Role
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(authority = RULIB)
degree grantor
Name
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NamePart
Graduate School - New Brunswick
Role
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school
TypeOfResource
Text
Genre
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theses
OriginInfo
DateCreated
(qualifier = exact)
2013
DateOther
(qualifier = exact);
(type = degree)
2013-05
Place
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(type = code)
xx
Language
LanguageTerm
(authority = ISO639-2b);
(type = code)
eng
Abstract
(type = abstract)
Nanocapillaries nd increasing use in a variety of applications including, protein translo- cation dynamics, protein sequencing, and other nano uidic studies. All of these appli- cations are a ected by the geometry of the nanopore and the molecular species found within. This dissertation develops a new equivalent circuit model to determine the geometry of nanocapillaries. This model is derived to include the e ects of a varying nanocapillary radius, along with the capacitive double layer within the nanocpaillary. The model is tested by using electrochemical impedance spectroscopy on a nanocapil- lary array membrane. The resulting values extracted from the model t are consistent with the manufacturer's speci ed geometry. The model is then further developed to determine the impedance of proteins. This is accomplished by modeling the protein as a cylinder and inserting this into our above mentioned model. By exploiting alternat- ing regions of surface charge density on the protein this model will allow for the rapid sequencing of proteins.
Subject
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Topic
Chemistry and Chemical Biology
RelatedItem
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Title
Rutgers University Electronic Theses and Dissertations
Identifier
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ETD_4520
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electronic resource
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application/pdf
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Extent
xxi, 117 p. : ill.
Note
(type = degree)
Ph.D.
Note
(type = bibliography)
Includes bibliographical references
Note
(type = statement of responsibility)
by Michael J. Vitarelli Jr.
Subject
(authority = ETD-LCSH)
Topic
Electrical impedance tomography
Subject
(authority = ETD-LCSH)
Topic
Impedance spectroscopy
Subject
(authority = ETD-LCSH)
Topic
Nanochemistry
Identifier
(type = hdl)
http://hdl.rutgers.edu/1782.1/rucore10001600001.ETD.000069008
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TitleInfo
Title
Graduate School - New Brunswick Electronic Theses and Dissertations
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rucore19991600001
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(displayLabel = Rutgers, The State University of New Jersey)
NjNbRU
Identifier
(type = doi)
doi:10.7282/T3Z89B03
Genre
(authority = ExL-Esploro)
ETD doctoral
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Rights
RightsDeclaration
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The author owns the copyright to this work.
RightsHolder
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Name
FamilyName
Vitarelli
GivenName
Michael
Role
Copyright Holder
RightsEvent
Type
Permission or license
DateTime
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(qualifier = exact);
(point = start)
2013-02-11 13:51:36
AssociatedEntity
Name
Michael Vitarelli
Role
Copyright holder
Affiliation
Rutgers University. Graduate School - New Brunswick
AssociatedObject
Type
License
Name
Author Agreement License
Detail
I hereby grant to the Rutgers University Libraries and to my school the non-exclusive right to archive, reproduce and distribute my thesis or dissertation, in whole or in part, and/or my abstract, in whole or in part, in and from an electronic format, subject to the release date subsequently stipulated in this submittal form and approved by my school. I represent and stipulate that the thesis or dissertation and its abstract are my original work, that they do not infringe or violate any rights of others, and that I make these grants as the sole owner of the rights to my thesis or dissertation and its abstract. I represent that I have obtained written permissions, when necessary, from the owner(s) of each third party copyrighted matter to be included in my thesis or dissertation and will supply copies of such upon request by my school. I acknowledge that RU ETD and my school will not distribute my thesis or dissertation or its abstract if, in their reasonable judgment, they believe all such rights have not been secured. I acknowledge that I retain ownership rights to the copyright of my work. I also retain the right to use all or part of this thesis or dissertation in future works, such as articles or books.
Copyright
Status
Copyright protected
Availability
Status
Open
Reason
Permission or license
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Technical
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windows xp
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