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Small gases and hydrocarbon adsorption and separation in microporous metal organic frameworks (MMOFs)
Descriptive
TitleInfo
Title
Small gases and hydrocarbon adsorption and separation in microporous metal organic frameworks (MMOFs)
Name
(type = personal)
NamePart
(type = family)
Wu
NamePart
(type = given)
Haohan
NamePart
(type = date)
1984-
DisplayForm
Haohan Wu
Role
RoleTerm
(authority = RULIB)
author
Name
(type = personal)
NamePart
(type = family)
Li
NamePart
(type = given)
Jing
DisplayForm
Jing Li
Affiliation
Advisory Committee
Role
RoleTerm
(authority = RULIB)
chair
Name
(type = personal)
NamePart
(type = family)
Brennan
NamePart
(type = given)
John
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John Brennan
Affiliation
Advisory Committee
Role
RoleTerm
(authority = RULIB)
internal member
Name
(type = personal)
NamePart
(type = family)
Garfunkel
NamePart
(type = given)
Eric L
DisplayForm
Eric L Garfunkel
Affiliation
Advisory Committee
Role
RoleTerm
(authority = RULIB)
internal member
Name
(type = personal)
NamePart
(type = family)
Riman
NamePart
(type = given)
Richard E
DisplayForm
Richard E Riman
Affiliation
Advisory Committee
Role
RoleTerm
(authority = RULIB)
outside member
Name
(type = corporate)
NamePart
Rutgers University
Role
RoleTerm
(authority = RULIB)
degree grantor
Name
(type = corporate)
NamePart
Graduate School - New Brunswick
Role
RoleTerm
(authority = RULIB)
school
TypeOfResource
Text
Genre
(authority = marcgt)
theses
OriginInfo
DateCreated
(qualifier = exact)
2013
DateOther
(qualifier = exact);
(type = degree)
2013-05
Place
PlaceTerm
(type = code)
xx
Language
LanguageTerm
(authority = ISO639-2b);
(type = code)
eng
Abstract
(type = abstract)
Microporous Metal Organic Frameworks (MMOFs) materials are very effective and efficient adsorbents for gas adsorption and separation due to their high surface area, large pore volume and relative low heat capacity. In this work, we focus on small gases and hydrocarbon adsorption and separation properties in MMOFs which typically have pore size smaller than 20Å. Nitrogen and argon adsorption isotherms were collected at 77K and 87K respectively for porosity characterization, e. g. surface area, pore volume and pore size distribution. Single component isotherms of small gases of CO2, N2, O2, H2, O2, Alkanes (CnH2n+2) and Alkenes (CnH2n) were collected at ambient condition to preliminarily evaluate gas adsorption and separation properties. After screening, mixed gas adsorption and breakthrough experiment were performed using promising MMOFs candidates in order to mimic the real world situation. Besides experiment, molecular simulation was studied in aid of learning adsorption behavior and separation mechanism in depth. An interesting phenomena, so called “commensurate adsorption”, was recognized and summarized in this thesis.
Subject
(authority = RUETD)
Topic
Chemistry and Chemical Biology
RelatedItem
(type = host)
TitleInfo
Title
Rutgers University Electronic Theses and Dissertations
Identifier
(type = RULIB)
ETD
Identifier
ETD_4552
PhysicalDescription
Form
(authority = gmd)
electronic resource
InternetMediaType
application/pdf
InternetMediaType
text/xml
Extent
xxiv, 138 p. : ill.
Note
(type = degree)
Ph.D.
Note
(type = bibliography)
Includes bibliographical references
Note
(type = statement of responsibility)
by Haohan Wu
Subject
(authority = ETD-LCSH)
Topic
Gases--Absorption and adsorption
Subject
(authority = ETD-LCSH)
Topic
Gases--Separation
Identifier
(type = hdl)
http://hdl.rutgers.edu/1782.1/rucore10001600001.ETD.000069006
RelatedItem
(type = host)
TitleInfo
Title
Graduate School - New Brunswick Electronic Theses and Dissertations
Identifier
(type = local)
rucore19991600001
Location
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(authority = marcorg);
(displayLabel = Rutgers, The State University of New Jersey)
NjNbRU
Identifier
(type = doi)
doi:10.7282/T3N01547
Genre
(authority = ExL-Esploro)
ETD doctoral
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Rights
RightsDeclaration
(ID = rulibRdec0006)
The author owns the copyright to this work.
RightsHolder
(type = personal)
Name
FamilyName
Wu
GivenName
Haohan
Role
Copyright Holder
RightsEvent
Type
Permission or license
DateTime
(encoding = w3cdtf);
(qualifier = exact);
(point = start)
2013-03-26 16:50:50
AssociatedEntity
Name
Haohan Wu
Role
Copyright holder
Affiliation
Rutgers University. Graduate School - New Brunswick
AssociatedObject
Type
License
Name
Author Agreement License
Detail
I hereby grant to the Rutgers University Libraries and to my school the non-exclusive right to archive, reproduce and distribute my thesis or dissertation, in whole or in part, and/or my abstract, in whole or in part, in and from an electronic format, subject to the release date subsequently stipulated in this submittal form and approved by my school. I represent and stipulate that the thesis or dissertation and its abstract are my original work, that they do not infringe or violate any rights of others, and that I make these grants as the sole owner of the rights to my thesis or dissertation and its abstract. I represent that I have obtained written permissions, when necessary, from the owner(s) of each third party copyrighted matter to be included in my thesis or dissertation and will supply copies of such upon request by my school. I acknowledge that RU ETD and my school will not distribute my thesis or dissertation or its abstract if, in their reasonable judgment, they believe all such rights have not been secured. I acknowledge that I retain ownership rights to the copyright of my work. I also retain the right to use all or part of this thesis or dissertation in future works, such as articles or books.
Copyright
Status
Copyright protected
Availability
Status
Open
Reason
Permission or license
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Technical
RULTechMD
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ContentModel
ETD
OperatingSystem
(VERSION = 5.1)
windows xp
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