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Synthesis and property investigation of Schiff-base polycavitand nanocapsules
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Sun, Junling. Synthesis and property investigation of Schiff-base polycavitand nanocapsules. Retrieved from https://doi.org/doi:10.7282/T33776RF

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TitleSynthesis and property investigation of Schiff-base polycavitand nanocapsules
NameSun, Junling (author); Warmuth, Ralf (chair); Williams, Lawrence J. (internal member); Uhrich, Kathryn E. (internal member); Pan, Long (outside member); Rutgers University; Graduate School - New Brunswick
Date Created2013
Other Date2013-10 (degree)
SubjectChemistry and Chemical Biology, Nanocapsules--Design, Microencapsulation, Schiff bases, Chemical tests and reagents
Extentxx, 339 p. : ill.
DescriptionDisclosed are studies on the design and synthesis of polycavitand nanocapsules and their encapsulation properties. In Chapter 1, a general overview about capsular molecules is presented. In Chapter 2, the synthesis, characterization and chiral guest recognition of chiral tetracavitand nanocapsules and chiral hemicarcerands are described. For tetracavitand nanocapsule 41a, a two-step enantiomerization process is discussed. In Chapter 3, the rational design and synthesis of giant nanocapsules, including octahedral and rhombicuboctahedral nanocapsules is discussed. These nanocapsules formed quantitatively from condensation reactions between deep cavitands and linear aromatic linkers. In Chapter 4, effective molarities (EMs) of a series of hemicarcerands and nanocapsules were measured. The results show that solvents and the linker rigidity play an important role in the formation of hemicarcerands and EMs of nanocapsules 23, 65a, 67a and 69 are mainly controlled by entropy. Furthermore, stepwise EMs of hemicarcerands 20b, 20d and 20g are discussed, too. In Chapter 5, the synthesis of hemicarcerands through liquid-assisted grinding (LAG) is described. Furthermore, encapsulation inside hemicarcerands 20b, 20d and 20g by grinding is discussed. In Chapter 6, water-soluble acylhydrazone rhombicuboctahedral nanocapsules were synthesized. Preliminary results of protein encapsulation are also presented.
NotePh.D.
NoteIncludes bibliographical references
NoteIncludes vita
Noteby Junling Sun
Genretheses, ETD doctoral
Persistent URLhttps://doi.org/doi:10.7282/T33776RF
Languageeng
CollectionGraduate School - New Brunswick Electronic Theses and Dissertations
Organization NameRutgers, The State University of New Jersey
RightsThe author owns the copyright to this work.
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