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Synthesis and property investigation of Schiff-base polycavitand nanocapsules
Descriptive
TitleInfo
Title
Synthesis and property investigation of Schiff-base polycavitand nanocapsules
Name
(type = personal)
NamePart
(type = family)
Sun
NamePart
(type = given)
Junling
NamePart
(type = date)
1983-
DisplayForm
Junling Sun
Role
RoleTerm
(authority = RULIB)
author
Name
(type = personal)
NamePart
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Warmuth
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(type = given)
Ralf
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Ralf Warmuth
Affiliation
Advisory Committee
Role
RoleTerm
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chair
Name
(type = personal)
NamePart
(type = family)
Williams
NamePart
(type = given)
Lawrence J.
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Lawrence J. Williams
Affiliation
Advisory Committee
Role
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(authority = RULIB)
internal member
Name
(type = personal)
NamePart
(type = family)
Uhrich
NamePart
(type = given)
Kathryn E.
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Kathryn E. Uhrich
Affiliation
Advisory Committee
Role
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(authority = RULIB)
internal member
Name
(type = personal)
NamePart
(type = family)
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Long
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Long Pan
Affiliation
Advisory Committee
Role
RoleTerm
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outside member
Name
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NamePart
Rutgers University
Role
RoleTerm
(authority = RULIB)
degree grantor
Name
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NamePart
Graduate School - New Brunswick
Role
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school
TypeOfResource
Text
Genre
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theses
OriginInfo
DateCreated
(qualifier = exact)
2013
DateOther
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(type = degree)
2013-10
Place
PlaceTerm
(type = code)
xx
Language
LanguageTerm
(authority = ISO639-2b);
(type = code)
eng
Abstract
(type = abstract)
Disclosed are studies on the design and synthesis of polycavitand nanocapsules and their encapsulation properties. In Chapter 1, a general overview about capsular molecules is presented. In Chapter 2, the synthesis, characterization and chiral guest recognition of chiral tetracavitand nanocapsules and chiral hemicarcerands are described. For tetracavitand nanocapsule 41a, a two-step enantiomerization process is discussed. In Chapter 3, the rational design and synthesis of giant nanocapsules, including octahedral and rhombicuboctahedral nanocapsules is discussed. These nanocapsules formed quantitatively from condensation reactions between deep cavitands and linear aromatic linkers. In Chapter 4, effective molarities (EMs) of a series of hemicarcerands and nanocapsules were measured. The results show that solvents and the linker rigidity play an important role in the formation of hemicarcerands and EMs of nanocapsules 23, 65a, 67a and 69 are mainly controlled by entropy. Furthermore, stepwise EMs of hemicarcerands 20b, 20d and 20g are discussed, too. In Chapter 5, the synthesis of hemicarcerands through liquid-assisted grinding (LAG) is described. Furthermore, encapsulation inside hemicarcerands 20b, 20d and 20g by grinding is discussed. In Chapter 6, water-soluble acylhydrazone rhombicuboctahedral nanocapsules were synthesized. Preliminary results of protein encapsulation are also presented.
Subject
(authority = RUETD)
Topic
Chemistry and Chemical Biology
Subject
(authority = ETD-LCSH)
Topic
Nanocapsules--Design
Subject
(authority = ETD-LCSH)
Topic
Microencapsulation
Subject
(authority = ETD-LCSH)
Topic
Schiff bases
Subject
(authority = ETD-LCSH)
Topic
Chemical tests and reagents
RelatedItem
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Title
Rutgers University Electronic Theses and Dissertations
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Identifier
ETD_4945
PhysicalDescription
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electronic resource
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application/pdf
InternetMediaType
text/xml
Extent
xx, 339 p. : ill.
Note
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Ph.D.
Note
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Includes bibliographical references
Note
(type = vita)
Includes vita
Note
(type = statement of responsibility)
by Junling Sun
Subject
(authority = ETD-LCSH)
RelatedItem
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TitleInfo
Title
Graduate School - New Brunswick Electronic Theses and Dissertations
Identifier
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rucore19991600001
Location
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(displayLabel = Rutgers, The State University of New Jersey)
NjNbRU
Identifier
(type = doi)
doi:10.7282/T33776RF
Genre
(authority = ExL-Esploro)
ETD doctoral
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Rights
RightsDeclaration
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The author owns the copyright to this work.
RightsHolder
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Name
FamilyName
Sun
GivenName
Junling
Role
Copyright Holder
RightsEvent
Type
Permission or license
DateTime
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(qualifier = exact);
(point = start)
2013-08-21 16:15:11
AssociatedEntity
Name
Junling Sun
Role
Copyright holder
Affiliation
Rutgers University. Graduate School - New Brunswick
AssociatedObject
Type
License
Name
Author Agreement License
Detail
I hereby grant to the Rutgers University Libraries and to my school the non-exclusive right to archive, reproduce and distribute my thesis or dissertation, in whole or in part, and/or my abstract, in whole or in part, in and from an electronic format, subject to the release date subsequently stipulated in this submittal form and approved by my school. I represent and stipulate that the thesis or dissertation and its abstract are my original work, that they do not infringe or violate any rights of others, and that I make these grants as the sole owner of the rights to my thesis or dissertation and its abstract. I represent that I have obtained written permissions, when necessary, from the owner(s) of each third party copyrighted matter to be included in my thesis or dissertation and will supply copies of such upon request by my school. I acknowledge that RU ETD and my school will not distribute my thesis or dissertation or its abstract if, in their reasonable judgment, they believe all such rights have not been secured. I acknowledge that I retain ownership rights to the copyright of my work. I also retain the right to use all or part of this thesis or dissertation in future works, such as articles or books.
Copyright
Status
Copyright protected
Availability
Status
Open
Reason
Permission or license
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Technical
RULTechMD
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ContentModel
ETD
OperatingSystem
(VERSION = 5.1)
windows xp
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