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Catalytic activation of carbon–hydrogen and carbon–oxygen bonds
Descriptive
TitleInfo
Title
Catalytic activation of carbon–hydrogen and carbon–oxygen bonds
Name
(type = personal)
NamePart
(type = family)
Haibach
NamePart
(type = given)
Michael Clement
DisplayForm
Michael Haibach
Role
RoleTerm
(authority = RULIB)
author
Name
(type = personal)
NamePart
(type = family)
Goldman
NamePart
(type = given)
Alan S
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Alan S Goldman
Affiliation
Advisory Committee
Role
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chair
Name
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NamePart
(type = family)
Seidel
NamePart
(type = given)
Daniel
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Daniel Seidel
Affiliation
Advisory Committee
Role
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internal member
Name
(type = personal)
NamePart
(type = family)
Krogh-Jespersen
NamePart
(type = given)
Karsten
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Karsten Krogh-Jespersen
Affiliation
Advisory Committee
Role
RoleTerm
(authority = RULIB)
internal member
Name
(type = personal)
NamePart
(type = family)
Anthony
NamePart
(type = given)
Linda J
DisplayForm
Linda J Anthony
Affiliation
Advisory Committee
Role
RoleTerm
(authority = RULIB)
outside member
Name
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NamePart
Rutgers University
Role
RoleTerm
(authority = RULIB)
degree grantor
Name
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NamePart
Graduate School - New Brunswick
Role
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school
TypeOfResource
Text
Genre
(authority = marcgt)
theses
OriginInfo
DateCreated
(qualifier = exact)
2014
DateOther
(qualifier = exact);
(type = degree)
2014-10
CopyrightDate
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2014
Language
LanguageTerm
(authority = ISO639-2b);
(type = code)
eng
Abstract
(type = abstract)
Efficient catalytic methods for the transformation of C–H, O–H, and C–O bonds are key to the efficient generation of both complex molecules and commodity chemicals, and for the processing of biomass. The work presented in this dissertation attempts to address these various goals using organocatalytic and organometallic approaches. Several new types of reactions have been developed: the hydride shift-triggered C–H functionalization using a bisnucleophile, the organometallic-catalyzed intermolecular olefin hydroaryloxylation, and the atom-economic C–O bond cleavage of aryl alkyl ethers. A new type of POP pincer ligand was developed and applied to investigate pincer rhodium hydride complexes, leading to the discovery of a robust olefin isomerization catalyst.
Subject
(authority = RUETD)
Topic
Chemistry and Chemical Biology
Subject
(authority = ETD-LCSH)
Topic
Carbon
Subject
(authority = ETD-LCSH)
Topic
Hydrogen
Subject
(authority = ETD-LCSH)
Topic
Catalysts
RelatedItem
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TitleInfo
Title
Rutgers University Electronic Theses and Dissertations
Identifier
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ETD
Identifier
ETD_5902
PhysicalDescription
Form
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electronic resource
InternetMediaType
application/pdf
InternetMediaType
text/xml
Extent
1 online resource (vi, 149 p. : ill.)
Note
(type = degree)
Ph.D.
Note
(type = bibliography)
Includes bibliographical references
Note
(type = statement of responsibility)
by Michael Clement Haibach
RelatedItem
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TitleInfo
Title
Graduate School - New Brunswick Electronic Theses and Dissertations
Identifier
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rucore19991600001
Location
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NjNbRU
Identifier
(type = doi)
doi:10.7282/T3MK6BCW
Genre
(authority = ExL-Esploro)
ETD doctoral
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Rights
RightsDeclaration
(ID = rulibRdec0006)
The author owns the copyright to this work.
RightsHolder
(type = personal)
Name
FamilyName
Haibach
GivenName
Michael
MiddleName
Clement
Role
Copyright Holder
RightsEvent
Type
Permission or license
DateTime
(encoding = w3cdtf);
(qualifier = exact);
(point = start)
2014-09-25 10:47:48
AssociatedEntity
Name
Michael Haibach
Role
Copyright holder
Affiliation
Rutgers University. Graduate School - New Brunswick
AssociatedObject
Type
License
Name
Author Agreement License
Detail
I hereby grant to the Rutgers University Libraries and to my school the non-exclusive right to archive, reproduce and distribute my thesis or dissertation, in whole or in part, and/or my abstract, in whole or in part, in and from an electronic format, subject to the release date subsequently stipulated in this submittal form and approved by my school. I represent and stipulate that the thesis or dissertation and its abstract are my original work, that they do not infringe or violate any rights of others, and that I make these grants as the sole owner of the rights to my thesis or dissertation and its abstract. I represent that I have obtained written permissions, when necessary, from the owner(s) of each third party copyrighted matter to be included in my thesis or dissertation and will supply copies of such upon request by my school. I acknowledge that RU ETD and my school will not distribute my thesis or dissertation or its abstract if, in their reasonable judgment, they believe all such rights have not been secured. I acknowledge that I retain ownership rights to the copyright of my work. I also retain the right to use all or part of this thesis or dissertation in future works, such as articles or books.
Copyright
Status
Copyright protected
Availability
Status
Open
Reason
Permission or license
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Technical
RULTechMD
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ContentModel
ETD
OperatingSystem
(VERSION = 5.1)
windows xp
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