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Second generation tris(2-pyridyl)borate ligands
Descriptive
TitleInfo
Title
Second generation tris(2-pyridyl)borate ligands
SubTitle
toward supramolecular polymeric materials
Name
(type = personal)
NamePart
(type = family)
Jeong
NamePart
(type = given)
So Yi
NamePart
(type = date)
1984-
DisplayForm
So Yi Jeong
Role
RoleTerm
(authority = RULIB)
author
Name
(type = personal)
NamePart
(type = family)
Jäkle
NamePart
(type = given)
Frieder
DisplayForm
Frieder Jäkle
Affiliation
Advisory Committee
Role
RoleTerm
(authority = RULIB)
chair
Name
(type = personal)
NamePart
(type = family)
Sheridan
NamePart
(type = given)
John B.
DisplayForm
John B. Sheridan
Affiliation
Advisory Committee
Role
RoleTerm
(authority = RULIB)
co-chair
Name
(type = personal)
NamePart
(type = family)
Lalancette
NamePart
(type = given)
Roger A.
DisplayForm
Roger A. Lalancette
Affiliation
Advisory Committee
Role
RoleTerm
(authority = RULIB)
internal member
Name
(type = corporate)
NamePart
Rutgers University
Role
RoleTerm
(authority = RULIB)
degree grantor
Name
(type = corporate)
NamePart
Graduate School - Newark
Role
RoleTerm
(authority = RULIB)
school
TypeOfResource
Text
Genre
(authority = marcgt)
theses
OriginInfo
DateCreated
(qualifier = exact)
2014
DateOther
(qualifier = exact);
(type = degree)
2014-10
CopyrightDate
(encoding = w3cdtf)
2014
Place
PlaceTerm
(type = code)
xx
Language
LanguageTerm
(authority = ISO639-2b);
(type = code)
eng
Abstract
(type = abstract)
Supramolecular metallopolymers are generally synthesized by the self-assembly polymerization of ditopic ligands through metal-ligand binding, which is a reversible process in many cases. Supramolecular metallopolymers can provide a strong impact in polymer chemistry and materials science because of the diverse applications in self-healing, optical, electronic, and magnetic materials. The Jäkle group has recently introduced the first examples of tris(2-pyridyl)borates (Tpyb) as a new class of tridentate ligands. These new “scorpionate”-type ligands are promising because of their anticipated strong coordinating ability toward main group and transition metals, the chemical tunability, and the high stability in comparison to commonly used tris(2-pyrazolylborate)s. In addition to that, the negative charge of the tridentate ligand results in neutral complexes with metal (II) ions, which contrasts the behavior of widely used terpyridine ligands. Based on these considerations, numerous applications in the fields of materials chemistry and catalysis are anticipated. However, these scorpionate type ligands have not yet been studied in supramolecular chemistry. Therefore, this thesis is focused on the development of second generation tris(2-pyridyl)borate (Tpyb) ligands, where our aim is to utilize these ligands as new building blocks in the generation of supramolecular metallopolymers. The synthesis, characterization and metal complexation behavior of this new class of ligands will be discussed in this thesis. Tpyb ligands that contain additional functional groups X such as silyl and iodo groups are described. The structures of all the ligands were confirmed by multinuclear NMR spectroscopy, high-resolution MALDI mass spectrometry, and single crystal X-ray crystallography. The corresponding metal complexes (Tpyb)2M (M = Fe, Ru) were prepared and characterized by multinuclear NMR spectroscopy, and high-resolution MALDI mass spectrometry. The properties of these metal complexes were further studied by cyclic voltammetry (CV) and UV-vis spectroscopy. Finally, a fluorene-based bitopic derivate is presented as a building block for functional metal-containing polymers.
Subject
(authority = RUETD)
Topic
Chemistry
Subject
(authority = ETD-LCSH)
Topic
Supramolecular chemistry
Subject
(authority = ETD-LCSH)
Topic
Ligands (Biochemistry)
RelatedItem
(type = host)
TitleInfo
Title
Rutgers University Electronic Theses and Dissertations
Identifier
(type = RULIB)
ETD
Identifier
ETD_5824
PhysicalDescription
Form
(authority = gmd)
electronic resource
InternetMediaType
application/pdf
InternetMediaType
text/xml
Extent
1 online resource (xii, 54 p. : ill.)
Note
(type = degree)
M.S.
Note
(type = bibliography)
Includes bibliographical references
Note
(type = vita)
Includes vita
Note
(type = statement of responsibility)
by So Yi Jeong
RelatedItem
(type = host)
TitleInfo
Title
Graduate School - Newark Electronic Theses and Dissertations
Identifier
(type = local)
rucore10002600001
Location
PhysicalLocation
(authority = marcorg);
(displayLabel = Rutgers, The State University of New Jersey)
NjNbRU
Identifier
(type = doi)
doi:10.7282/T3M0473F
Genre
(authority = ExL-Esploro)
ETD graduate
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Rights
RightsDeclaration
(ID = rulibRdec0006)
The author owns the copyright to this work.
RightsHolder
(type = personal)
Name
FamilyName
Jeong
GivenName
So Yi
Role
Copyright Holder
RightsEvent
Type
Permission or license
DateTime
(encoding = w3cdtf);
(qualifier = exact);
(point = start)
2014-09-09 20:45:48
AssociatedEntity
Name
So Yi Jeong
Role
Copyright holder
Affiliation
Rutgers University. Graduate School - Newark
AssociatedObject
Type
License
Name
Author Agreement License
Detail
I hereby grant to the Rutgers University Libraries and to my school the non-exclusive right to archive, reproduce and distribute my thesis or dissertation, in whole or in part, and/or my abstract, in whole or in part, in and from an electronic format, subject to the release date subsequently stipulated in this submittal form and approved by my school. I represent and stipulate that the thesis or dissertation and its abstract are my original work, that they do not infringe or violate any rights of others, and that I make these grants as the sole owner of the rights to my thesis or dissertation and its abstract. I represent that I have obtained written permissions, when necessary, from the owner(s) of each third party copyrighted matter to be included in my thesis or dissertation and will supply copies of such upon request by my school. I acknowledge that RU ETD and my school will not distribute my thesis or dissertation or its abstract if, in their reasonable judgment, they believe all such rights have not been secured. I acknowledge that I retain ownership rights to the copyright of my work. I also retain the right to use all or part of this thesis or dissertation in future works, such as articles or books.
RightsEvent
DateTime
(encoding = w3cdtf);
(qualifier = exact);
(point = start)
2014-10-31
DateTime
(encoding = w3cdtf);
(qualifier = exact);
(point = end)
2016-10-30
Type
Embargo
Detail
Access to this PDF has been restricted at the author's request. It will be publicly available after October 30th, 2016.
Copyright
Status
Copyright protected
Availability
Status
Open
Reason
Permission or license
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Technical
RULTechMD
(ID = TECHNICAL1)
ContentModel
ETD
OperatingSystem
(VERSION = 5.1)
windows xp
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