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Microwave Enabled One-Pot, One-Step Fabrication and Nitrogen Doping of Holey Graphene Oxide for Catalytic Applications

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TypeOfResource
Text
TitleInfo
Title
Microwave Enabled One-Pot, One-Step Fabrication and Nitrogen Doping of Holey Graphene Oxide for Catalytic Applications
Name (type = personal)
NamePart (type = family)
Patel
NamePart (type = given)
Mehulkumar A.
Affiliation
Chemistry (Newark), Rutgers University
Role
RoleTerm (authority = marcrt); (type = text)
author
Name (authority = orcid); (authorityURI = http://id.loc.gov/vocabulary/identifiers/orcid.html); (type = personal); (valueURI = http://orcid.org/0000-0002-0604-9441)
NamePart (type = family)
Feng
NamePart (type = given)
Wenchun
Affiliation
University of Michigan
Role
RoleTerm (authority = marcrt); (type = text)
author
Name (type = personal)
NamePart (type = family)
Savaram
NamePart (type = given)
Keerthi
Affiliation
Chemistry (Newark), Rutgers University
Role
RoleTerm (authority = marcrt); (type = text)
author
Name (type = personal)
NamePart (type = family)
Khoshi
NamePart (type = given)
M. Reza
Affiliation
Chemistry (Newark), Rutgers University
Role
RoleTerm (authority = marcrt); (type = text)
author
Name (type = personal)
NamePart (type = family)
Huang
NamePart (type = given)
Ruiming
Affiliation
Chemistry (Newark), Rutgers University
Role
RoleTerm (authority = marcrt); (type = text)
author
Name (type = personal)
NamePart (type = family)
Sun
NamePart (type = given)
Jing
Affiliation
Chemistry (Newark), Rutgers University
Role
RoleTerm (authority = marcrt); (type = text)
author
Name (type = personal)
NamePart (type = family)
Rabie
NamePart (type = given)
Emann
Affiliation
Chemistry (Newark), Rutgers University
Role
RoleTerm (authority = marcrt); (type = text)
author
Name (type = personal)
NamePart (type = family)
Flach
NamePart (type = given)
Carol
Affiliation
Chemistry (Newark), Rutgers University
Role
RoleTerm (authority = marcrt); (type = text)
author
Name (type = personal)
NamePart (type = family)
Mendelsohn
NamePart (type = given)
Richard
Affiliation
Chemistry (Newark), Rutgers University
Role
RoleTerm (authority = marcrt); (type = text)
author
Name (type = personal)
NamePart (type = family)
Garfunkel
NamePart (type = given)
Eric
Affiliation
Chemistry & Chemical Biology, Rutgers University
Role
RoleTerm (authority = marcrt); (type = text)
author
Name (type = personal)
NamePart (type = family)
He
NamePart (type = given)
Huixin
Affiliation
Chemistry (Newark), Rutgers University
Role
RoleTerm (authority = marcrt); (type = text)
author
Name (authority = RutgersOrg-Department); (type = corporate)
NamePart
Chemistry (Newark)
Name (authority = RutgersOrg-School); (type = corporate)
NamePart
Newark College of Arts and Sciences
Name (authority = RutgersOrg-School); (type = corporate)
NamePart
School of Arts and Sciences (SAS) (New Brunswick)
Name (authority = RutgersOrg-Department); (type = corporate)
NamePart
Chemistry & Chemical Biology
Genre (authority = RULIB-FS)
Article, Refereed
Genre (authority = NISO JAV)
Accepted Manuscript (AM)
OriginInfo
DateCreated (encoding = w3cdtf); (keyDate = yes); (qualifier = exact)
2015
Publisher
Wiley-VCH Verlag GmbH & Co
Abstract (type = Abstract)
The unique properties of holey graphene sheet, referred to graphene sheet with nanoholes in its basal plane, lead to wide range of applications, which cannot be achieved by its nonporous counterpart. However, its large scale solution based production requires graphene oxide (GO) or reduced GO (rGO) as starting materials, which take hours to days for their fabrication. Here, we report our unexpected discovery that GO with or without holes can be controllably, directly, and rapidly (tens of seconds) fabricated from graphite powder via a one-step-one-pot microwave assisted reaction with a production yield of 120 wt% of graphite. Furthermore, a fast and low temperature approach is developed for simultaneous nitrogen (N) doping and reduction of GO sheets. The N-doped holey rGO sheets demonstrate remarkable electrocatalytic capabilities toward electrochemical oxygen reduction reaction. The existence of the nanoholes not only provides a “short cut” for efficient mass transport, but also dramatically increases edges and surface area, therefore, creates more catalytic centers. The capability of rapid fabrication and N-doping as well as reduction of holey GO can lead us to develop efficient catalyst, which can replace previous coin metals for energy generation and storage, such as fuel cells and metal–air batteries
Language
LanguageTerm (authority = ISO 639-3:2007); (type = text)
English
PhysicalDescription
InternetMediaType
application/pdf
Extent
34 p.
Extension
DescriptiveEvent
Type
Citation
DateTime (encoding = w3cdtf)
2015
AssociatedObject
Name
Small
Type
Journal
Relationship
Has part
Detail
3358-3368
Identifier (type = volume and issue)
11(27)
Reference (type = url)
https://dx.doi.org/10.1002/smll.201403402
Extension
DescriptiveEvent
Type
Grant award
AssociatedEntity
Role
Funder
Name
National Science Foundation
AssociatedObject
Type
Grant number
Name
STTR 1346496
AssociatedObject
Type
Grant number
Name
CBET 1438493
Note (type = version identification)
This is the accepted version of the following article: Patel, M., Feng, W., Savaram, K., Khoshi, M. R., Huang, R., Sun, J., Rabie, E., Flach, C., Mendelsohn, R., Garfunkel, E. and He, H. (2015), Microwave Enabled One-Pot, One-Step Fabrication and Nitrogen Doping of Holey Graphene Oxide for Catalytic Applications. Small, 11: 3358–3368, which has been published in final form at https://dx.doi.org/10.1002/smll.201403402.
Note (type = peerReview)
Peer reviewed
Subject (authority = local)
Topic
Holey graphene sheet
Subject (authority = local)
Topic
Graphene oxide
Subject (authority = local)
Topic
Microwave irradiation
Subject (authority = local)
Topic
Heteroatom doping
Subject (authority = local)
Topic
Oxygen reduction reaction
Subject (authority = LCSH)
Topic
Graphene--Oxidation
Subject (authority = LCSH)
Topic
Radiation
Subject (authority = LCSH)
Topic
Microwaves
Subject (authority = LCSH)
Topic
Heterocyclic chemistry
RelatedItem (type = host)
TitleInfo
Title
Flach, Carol
Identifier (type = local)
rucore20171400001
RelatedItem (type = host)
TitleInfo
Title
Savaram, Keerthi
Identifier (type = local)
rucore30171700001
RelatedItem (type = host)
TitleInfo
Title
Mendelsohn, Richard
Identifier (type = local)
rucore30171800001
RelatedItem (type = host)
TitleInfo
Title
He, Huixin
Identifier (type = local)
rucore30171600001
RelatedItem (type = host)
TitleInfo
Title
Khoshi, Mohammadreza
Identifier (type = local)
rucore30171500001
RelatedItem (type = host)
TitleInfo
Title
Garfunkel, Eric
Identifier (type = local)
rucore30134900001
RelatedItem (type = host)
TitleInfo
Title
Patel, Mehulkumar A.
Identifier (type = local)
rucore30170300001
Location
PhysicalLocation (authority = marcorg); (displayLabel = Rutgers, The State University of New Jersey)
NjNbRU
Identifier (type = doi)
doi:10.7282/T3M90BKJ
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RightsDeclaration (AUTHORITY = FS); (ID = rulibRdec0004)
Copyright for scholarly resources published in RUcore is retained by the copyright holder. By virtue of its appearance in this open access medium, you are free to use this resource, with proper attribution, in educational and other non-commercial settings. Other uses, such as reproduction or republication, may require the permission of the copyright holder.
Copyright
Status
Copyright protected
Availability
Status
Open
Reason
Permission or license
RightsEvent
Type
Permission or license
AssociatedObject
Type
License
Name
Multiple author license v. 1
Detail
I hereby grant to Rutgers, The State University of New Jersey (Rutgers) the non-exclusive right to retain, reproduce, and distribute the deposited work (Work) in whole or in part, in and from its electronic format, without fee. This agreement does not represent a transfer of copyright to Rutgers.Rutgers may make and keep more than one copy of the Work for purposes of security, backup, preservation, and access and may migrate the Work to any medium or format for the purpose of preservation and access in the future. Rutgers will not make any alteration, other than as allowed by this agreement, to the Work.I represent and warrant to Rutgers that the Work is my original work. I also represent that the Work does not, to the best of my knowledge, infringe or violate any rights of others.I further represent and warrant that I have obtained all necessary rights to permit Rutgers to reproduce and distribute the Work and that any third-party owned content is clearly identified and acknowledged within the Work.By granting this license, I acknowledge that I have read and agreed to the terms of this agreement and all related RUcore and Rutgers policies.
RightsEvent
Type
Embargo
DateTime (point = start); (encoding = w3cdtf)
2015-10-13
DateTime (point = end); (encoding = w3cdtf)
2016-07-14
Detail
Access to this PDF has been restricted at the publisher's request. It will be publicly available after July 14, 2016. This journal requires a 12-month embargo from the date of official publication.
RightsHolder (type = corporate)
Name
WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Role
Copyright holder
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RULTechMD (ID = TECHNICAL1)
ContentModel
Document
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