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Selectivity for dimers in pentene oligomerization over acid zeolites

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TypeOfResource
Text
TitleInfo
Title
Selectivity for dimers in pentene oligomerization over acid zeolites
Name (authority = RutgersOrg-Department); (type = corporate)
NamePart
Chemical & Biochemical Engineering
Name (authority = RutgersOrg-School); (type = corporate)
NamePart
School of Engineering
Name (authority = RutgersOrg-Department); (type = corporate)
NamePart
Chemistry & Chemical Biology
Name (authority = RutgersOrg-School); (type = corporate)
NamePart
School of Arts and Sciences (SAS) (New Brunswick)
Genre (authority = RULIB-FS)
Article, Refereed
Genre (authority = NISO JAV)
Accepted Manuscript (AM)
Note (type = peerReview)
Peer reviewed
OriginInfo
Publisher
Elsevier
DateIssued (encoding = w3cdtf); (keyDate = yes); (qualifier = exact)
2016
Abstract (type = Abstract)
The reactions of 1-pentene over acid zeolites were investigated in the liquid phase at 473 K. The primary reactions were isomerization, dimerization, and subsequent cracking of dimers. Zeolites consisting of only 10-membered (MFI) or 12-membered rings (FAU, BEA) behaved similarly, with dimerization and subsequent cracking products observed. Zeolites possessing 8-membered ring pores (MOR, FER) showed very different selectivity from each other and from other zeolites. MOR showed almost complete conversion of C10 olefins, such that hexene and butene from cracking were the dominant products. FER showed high activity and selectivity for dimerization, with very small amounts of cracking products observed.
Language
LanguageTerm (authority = ISO 639-3:2007); (type = text)
English
PhysicalDescription
InternetMediaType
application/pdf
Extent
17 p.
Subject (authority = local)
Topic
1-pentene
Subject (authority = local)
Topic
Oligomerization
Subject (authority = LCSH)
Topic
Oligomers
Subject (authority = local)
Topic
Dimerization
Subject (authority = local)
Topic
Dimers
Subject (authority = LCSH)
Topic
Zeolites
Subject (authority = local)
Topic
Ferrierite
Subject (authority = LCSH)
Topic
Cracking process
Extension
DescriptiveEvent
Type
Citation
AssociatedObject
Name
Catalysis Communications
Type
Journal
Relationship
Has part
Reference (type = url)
http://dx.doi.org/10.1016/j.catcom.2015.11.012
Identifier (type = volume and issue)
75,
Detail
98-102
DateTime (encoding = w3cdtf)
2016
Name (type = personal)
NamePart (type = family)
Kulkarni
NamePart (type = given)
Atish
Affiliation
Chemical & Biochemical Engineering, Rutgers University
Role
RoleTerm (authority = marcrt); (type = text)
author
Name (authority = orcid); (authorityURI = http://id.loc.gov/vocabulary/identifiers/orcid.html); (type = personal); (valueURI = http://orcid.org/0000-0002-3911-3630)
NamePart (type = family)
Kuman
NamePart (type = given)
Akshai
Affiliation
Chemistry & Chemical Biology, Rutgers University
Role
RoleTerm (authority = marcrt); (type = text)
author
Name (authority = orcid); (authorityURI = http://id.loc.gov/vocabulary/identifiers/orcid.html); (type = personal); (valueURI = http://orcid.org/0000-0002-2774-710X)
NamePart (type = family)
Goldman
NamePart (type = given)
Alan S.
Affiliation
Chemistry & Chemical Biology, Rutgers University
Role
RoleTerm (authority = marcrt); (type = text)
author
Name (authority = orcid); (authorityURI = http://id.loc.gov/vocabulary/identifiers/orcid.html); (type = personal); (valueURI = http://orcid.org/0000-0002-5891-6375)
NamePart (type = family)
Celik
NamePart (type = given)
Fuat E.
Affiliation
Chemical & Biochemical Engineering, Rutgers University
Role
RoleTerm (authority = marcrt); (type = text)
author
RelatedItem (type = host)
TitleInfo
Title
Celik, Fuat E.
Identifier (type = local)
rucore30157200001
RelatedItem (type = host)
TitleInfo
Title
Kulkarni, Atish
Identifier (type = local)
rucore30208800001
RelatedItem (type = host)
TitleInfo
Title
Goldman, Alan S.
Identifier (type = local)
rucore30208700001
Location
PhysicalLocation (authority = marcorg); (displayLabel = Rutgers, The State University of New Jersey)
NjNbRU
Identifier (type = doi)
doi:10.7282/T3542QJN
Genre (authority = ExL-Esploro)
Accepted Manuscript
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Rights

RightsDeclaration (AUTHORITY = FS); (ID = rulibRdec0004)
Copyright for scholarly resources published in RUcore is retained by the copyright holder. By virtue of its appearance in this open access medium, you are free to use this resource, with proper attribution, in educational and other non-commercial settings. Other uses, such as reproduction or republication, may require the permission of the copyright holder.
Copyright
Status
Copyright protected
Availability
Status
Open
Reason
Permission or license
RightsEvent
Type
Permission or license
AssociatedObject
Type
License
Name
Multiple author license v. 1
Detail
I hereby grant to Rutgers, The State University of New Jersey (Rutgers) the non-exclusive right to retain, reproduce, and distribute the deposited work (Work) in whole or in part, in and from its electronic format, without fee. This agreement does not represent a transfer of copyright to Rutgers.Rutgers may make and keep more than one copy of the Work for purposes of security, backup, preservation, and access and may migrate the Work to any medium or format for the purpose of preservation and access in the future. Rutgers will not make any alteration, other than as allowed by this agreement, to the Work.I represent and warrant to Rutgers that the Work is my original work. I also represent that the Work does not, to the best of my knowledge, infringe or violate any rights of others.I further represent and warrant that I have obtained all necessary rights to permit Rutgers to reproduce and distribute the Work and that any third-party owned content is clearly identified and acknowledged within the Work.By granting this license, I acknowledge that I have read and agreed to the terms of this agreement and all related RUcore and Rutgers policies.
RightsEvent
Type
Embargo
DateTime (point = start); (encoding = w3cdtf)
2015-12-02
DateTime (point = end); (encoding = w3cdtf)
2018-02-05
Detail
Access to this PDF is restricted due to the journal publisher's policy. Articles in this journal are embargoed for 24 months from the date the article is formally published online in its final and fully citable form (i.e. online publication date). This version of the article is anticipated to be available after February 5, 2018.
RightsEvent
Type
Publication notice
Detail
© 2016. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/
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Technical

RULTechMD (ID = TECHNICAL1)
ContentModel
Document
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