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Investigation of physical and electrochemical properties of tantalum-doped beta niobium phosphate as an electrode for lithium batteries

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TitleInfo
Title
Investigation of physical and electrochemical properties of tantalum-doped beta niobium phosphate as an electrode for lithium batteries
Name (type = personal)
NamePart (type = family)
Lu
NamePart (type = given)
Matthew Yunching
NamePart (type = date)
1993-
DisplayForm
Matthew Yunching Lu
Role
RoleTerm (authority = RULIB)
author
Name (type = personal)
NamePart (type = family)
Amatucci
NamePart (type = given)
Glenn G
DisplayForm
Glenn G Amatucci
Affiliation
Advisory Committee
Role
RoleTerm (authority = RULIB)
chair
Name (type = personal)
NamePart (type = family)
Klein
NamePart (type = given)
Lisa
DisplayForm
Lisa Klein
Affiliation
Advisory Committee
Role
RoleTerm (authority = RULIB)
internal member
Name (type = personal)
NamePart (type = family)
Cosandey
NamePart (type = given)
Frederic
DisplayForm
Frederic Cosandey
Affiliation
Advisory Committee
Role
RoleTerm (authority = RULIB)
internal member
Name (type = corporate)
NamePart
Rutgers University
Role
RoleTerm (authority = RULIB)
degree grantor
Name (type = corporate)
NamePart
Graduate School - New Brunswick
Role
RoleTerm (authority = RULIB)
school
TypeOfResource
Text
Genre (authority = marcgt)
theses
OriginInfo
DateCreated (encoding = w3cdtf); (qualifier = exact)
2015
DateOther (qualifier = exact); (type = degree)
2015-10
CopyrightDate (encoding = w3cdtf); (qualifier = exact)
2015
Place
PlaceTerm (type = code)
xx
Language
LanguageTerm (authority = ISO639-2b); (type = code)
eng
Abstract (type = abstract)
Phosphate intercalation materials are an integral chemistry for secondary lithium-ion batteries. The demand for energy storage technologies with higher energy and power densities is ever increasing, indicating a necessity for the development of new battery chemistries. The robust nature of phosphate groups is a strong platform for the development of new lithium-ion battery chemistries. From here, β-NbPO5 is realized as a positive electrode material for lithium batteries. With an operating voltage circa 2V, β-NbPO5 has the potential to be either the positive or negative electrode. In this thesis, the electrochemical stability of β-NbPO5 is improved using two different methods of altering the voltage window and utilizing a Ta5+ ionic substitution to form β-TaxNb1-xPO5. Preliminary electrochemistry of the end member β-TaPO5 is reported for the first time. The flat voltage profile, excellent reversibility, and low polarization make β-TaxNb1-xPO5 a good candidate for a model reference electrode material.
Subject (authority = RUETD)
Topic
Materials Science and Engineering
Subject (authority = ETD-LCSH)
Topic
Lithium ion batteries
Subject (authority = ETD-LCSH)
Topic
Tantalum
RelatedItem (type = host)
TitleInfo
Title
Rutgers University Electronic Theses and Dissertations
Identifier (type = RULIB)
ETD
Identifier
ETD_6774
PhysicalDescription
Form (authority = gmd)
electronic resource
InternetMediaType
application/pdf
InternetMediaType
text/xml
Extent
1 online resource (xi, 60 p. : ill.)
Note (type = degree)
M.S.
Note (type = bibliography)
Includes bibliographical references
Note (type = statement of responsibility)
by Matthew Yunching Lu
RelatedItem (type = host)
TitleInfo
Title
Graduate School - New Brunswick Electronic Theses and Dissertations
Identifier (type = local)
rucore19991600001
Location
PhysicalLocation (authority = marcorg); (displayLabel = Rutgers, The State University of New Jersey)
NjNbRU
Identifier (type = doi)
doi:10.7282/T39Z96W3
Genre (authority = ExL-Esploro)
ETD graduate
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Rights

RightsDeclaration (ID = rulibRdec0006)
The author owns the copyright to this work.
RightsHolder (type = personal)
Name
FamilyName
Lu
GivenName
Matthew
MiddleName
Yunching
Role
Copyright Holder
RightsEvent
Type
Permission or license
DateTime (encoding = w3cdtf); (qualifier = exact); (point = start)
2015-09-24 13:35:27
AssociatedEntity
Name
Matthew Lu
Role
Copyright holder
Affiliation
Rutgers University. Graduate School - New Brunswick
AssociatedObject
Type
License
Name
Author Agreement License
Detail
I hereby grant to the Rutgers University Libraries and to my school the non-exclusive right to archive, reproduce and distribute my thesis or dissertation, in whole or in part, and/or my abstract, in whole or in part, in and from an electronic format, subject to the release date subsequently stipulated in this submittal form and approved by my school. I represent and stipulate that the thesis or dissertation and its abstract are my original work, that they do not infringe or violate any rights of others, and that I make these grants as the sole owner of the rights to my thesis or dissertation and its abstract. I represent that I have obtained written permissions, when necessary, from the owner(s) of each third party copyrighted matter to be included in my thesis or dissertation and will supply copies of such upon request by my school. I acknowledge that RU ETD and my school will not distribute my thesis or dissertation or its abstract if, in their reasonable judgment, they believe all such rights have not been secured. I acknowledge that I retain ownership rights to the copyright of my work. I also retain the right to use all or part of this thesis or dissertation in future works, such as articles or books.
RightsEvent
DateTime (encoding = w3cdtf); (qualifier = exact); (point = start)
2015-10-31
DateTime (encoding = w3cdtf); (qualifier = exact); (point = end)
2016-10-30
Type
Embargo
Detail
Access to this PDF has been restricted at the author's request. It will be publicly available after October 30th, 2016.
Copyright
Status
Copyright protected
Availability
Status
Open
Reason
Permission or license
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Technical

RULTechMD (ID = TECHNICAL1)
ContentModel
ETD
OperatingSystem (VERSION = 5.1)
windows xp
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