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Formation of enamines and 1,2 difunctionalized olefins via catalytic dehydrogenation by pincer-ir complexes
Descriptive
TitleInfo
Title
Formation of enamines and 1,2 difunctionalized olefins via catalytic dehydrogenation by pincer-ir complexes
Name
(type = personal)
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Lu
NamePart
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Yansong
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Yansong Lu
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author
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Goldman
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Alan S
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Alan S Goldman
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Advisory Committee
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chair
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Lipke
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Mark
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Mark Lipke
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Advisory Committee
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internal member
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Celik
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Fuat E
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Fuat E Celik
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Advisory Committee
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internal member
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Wilk
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Bogdan
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Bogdan Wilk
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Advisory Committee
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outside member
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Rutgers University
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degree grantor
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School of Graduate Studies
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school
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Text
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theses
OriginInfo
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2017
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2017-10
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2017
Place
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xx
Language
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eng
Abstract
(type = abstract)
Efficient pincer-ligated-iridium catalysts are reported for the dehydrogenation of amines to give enamines and for the dehydrogenation of 1,2-difunctionalized C-C linkages to give the corresponding 1,2-difunctionalized olefins. Isotope effect studies indicate that the rate-determining step is β-C-H bond cleavage following a pre-equilibrium cleavage of the α-C-H bond.
Subject
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Topic
Chemistry and Chemical Biology
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Title
Rutgers University Electronic Theses and Dissertations
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ETD
Identifier
ETD_8353
PhysicalDescription
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electronic resource
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application/pdf
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text/xml
Extent
1 online resource (vii, 31 p. : ill.)
Note
(type = degree)
Ph.D.
Note
(type = bibliography)
Includes bibliographical references
Subject
(authority = ETD-LCSH)
Topic
Iridium catalysts
Subject
(authority = ETD-LCSH)
Topic
Dehydrogenation
Note
(type = statement of responsibility)
by Yangsong Lu
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TitleInfo
Title
School of Graduate Studies Electronic Theses and Dissertations
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rucore10001600001
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NjNbRU
Identifier
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doi:10.7282/T3SX6HCZ
Genre
(authority = ExL-Esploro)
ETD doctoral
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Rights
RightsDeclaration
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The author owns the copyright to this work.
RightsHolder
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Name
FamilyName
Lu
GivenName
Yansong
Role
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Permission or license
DateTime
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2017-10-05 13:32:00
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Yansong Lu
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Affiliation
Rutgers University. School of Graduate Studies
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Type
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Author Agreement License
Detail
I hereby grant to the Rutgers University Libraries and to my school the non-exclusive right to archive, reproduce and distribute my thesis or dissertation, in whole or in part, and/or my abstract, in whole or in part, in and from an electronic format, subject to the release date subsequently stipulated in this submittal form and approved by my school. I represent and stipulate that the thesis or dissertation and its abstract are my original work, that they do not infringe or violate any rights of others, and that I make these grants as the sole owner of the rights to my thesis or dissertation and its abstract. I represent that I have obtained written permissions, when necessary, from the owner(s) of each third party copyrighted matter to be included in my thesis or dissertation and will supply copies of such upon request by my school. I acknowledge that RU ETD and my school will not distribute my thesis or dissertation or its abstract if, in their reasonable judgment, they believe all such rights have not been secured. I acknowledge that I retain ownership rights to the copyright of my work. I also retain the right to use all or part of this thesis or dissertation in future works, such as articles or books.
Copyright
Status
Copyright protected
Availability
Status
Open
Reason
Permission or license
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