Pickering foams, aqueous foams stabilized by solid particles, can be used as a precursor to fabricate solid porous polymers, ceramics, and composite materials. The fabrication process usually comprises of two subsequent steps of drying and solidification (e.g. sintering) after foam is prepared. Drying (or aging) in aqueous Pickering foams is a complex transport process which involves evaporation and drainage (induced by gravity) of the excess liquid along with deformation of the foam and possible formation of cracks caused by capillary-induced stresses. Crack formation is therefore depended on the drying conditions and the mechanical properties of sample. A comprehensive understanding of the drying process can provide us with predictive tools to select efficient process parameters (e.g. required drying time prior to sintering) as well as providing input prameters for developing numerical models. In this thesis, we first provide experimental data (end of drying time, average moisture content, and effective moisture diffusivity) on drying of Pickering foams stabilized by polymer particles under controlled conditions (i.e. relative humidity and temperature). Drying curves are presented for samples of various initial thicknesses and shapes on substrates of different hydrophobicity and temperatures. Moisture transport is represented via calculating the effective moisture diffusivity coefficients using method of slope. Also, we investigate drying for a bi-component Pickering foam prepared using Multi-walled Carbon Nanotubes (MWCNTs) and polymer particles. We show that the effective moisture diffusivity increases as the average moisture content decreases for all trials and that all data can be collapsed on a master curve. Also, effective moisture diffusivity increased as initial sample thickness as well as substrate temperature increase. On the other hand, effective moisture diffusivity does not depend strongly on the sample shape and MWCNTs concentration. In next part, we explore the effect of initial sample thickness and shape, substrate temperature and wettability, as well as MWCNTs concentration on the crack formations in the samples. We demonstrate that substrate wettability, initial sample thickness, and MWCNTs concentration have a strong influence on the formation and propagation of cracks. We found that decreasing the wettability of the substrate reduces crack formation. Also, increasing the initial sample thickness reduces crack formation. On the contrary, increasing the MWCNTs concentration increases crack formation for all types of substrates. We demonstrate that substrate temperature and sample shape do not seem to influence crack formation but these parameters influence the crack patterns. Such information can be beneficial in using these foams as a precursor to fabricate porous composite porous materials.
Subject (authority = RUETD)
Topic
Mechanical and Aerospace Engineering
RelatedItem (type = host)
TitleInfo
Title
Rutgers University Electronic Theses and Dissertations
Identifier (type = RULIB)
ETD
Identifier
ETD_8873
PhysicalDescription
Form (authority = gmd)
electronic resource
InternetMediaType
application/pdf
InternetMediaType
text/xml
Extent
1 online resource (xv, 131 p. : ill.)
Note (type = degree)
Ph.D.
Note (type = bibliography)
Includes bibliographical references
Note (type = statement of responsibility)
by Omer S. Alabidalkreem
RelatedItem (type = host)
TitleInfo
Title
School of Graduate Studies Electronic Theses and Dissertations
Identifier (type = local)
rucore10001600001
Location
PhysicalLocation (authority = marcorg); (displayLabel = Rutgers, The State University of New Jersey)
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