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Inorganic polymers made directly from minerals

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TitleInfo
Title
Inorganic polymers made directly from minerals
Name (type = personal)
NamePart (type = family)
Kazancioglu
NamePart (type = given)
Monika
NamePart (type = date)
1990-
DisplayForm
Monika Kazancioglu
Role
RoleTerm (authority = RULIB)
author
Name (type = personal)
NamePart (type = family)
Hara
NamePart (type = given)
Masanori
DisplayForm
Masanori Hara
Affiliation
Advisory Committee
Role
RoleTerm (authority = RULIB)
chair
Name (type = personal)
NamePart (type = family)
Shapley
NamePart (type = given)
Nina
DisplayForm
Nina Shapley
Affiliation
Advisory Committee
Role
RoleTerm (authority = RULIB)
internal member
Name (type = personal)
NamePart (type = family)
Dutt
NamePart (type = given)
Meenakshi
DisplayForm
Meenakshi Dutt
Affiliation
Advisory Committee
Role
RoleTerm (authority = RULIB)
internal member
Name (type = personal)
NamePart (type = family)
Lehman
NamePart (type = given)
Richard
DisplayForm
Richard Lehman
Affiliation
Advisory Committee
Role
RoleTerm (authority = RULIB)
outside member
Name (type = corporate)
NamePart
Rutgers University
Role
RoleTerm (authority = RULIB)
degree grantor
Name (type = corporate)
NamePart
School of Graduate Studies
Role
RoleTerm (authority = RULIB)
school
TypeOfResource
Text
Genre (authority = marcgt)
theses
OriginInfo
DateCreated (qualifier = exact)
2018
DateOther (qualifier = exact); (type = degree)
2018-10
CopyrightDate (encoding = w3cdtf)
2018
Language
LanguageTerm (authority = ISO639-2b); (type = code)
eng
Abstract (type = abstract)
This work seeks to develop the scientific knowledge by which conventional organic polymers can be replaced with their inorganic counterparts. It is aimed to synthesize silicate-based inorganic polymers directly from minerals, such as silica, which are readily available in nature (e.g., sands and rocks). Inorganic polymers decrease the dependence on crude oil and promise chemically more stable compounds than organic polymers. Having silicate as the backbone, the need for recycling is eliminated and the new materials are likely to be non-flammable and non-toxic. Specifically, we are developing a new class of polymers in which the backbone is comprised of ionic (primary) and secondary bonds. The high processing temperature of silica is first decreased via addition of metal ions (from a modifier, such as strontium oxide, rubidium oxide, calcium oxide, or potassium oxide) that serve to reduce the interchain bond strength, hence lowering the glass transition temperature (Tg); and providing additional free volume for the subsequent insertion of new moieties (i.e., ionic liquid). During this process, highly crosslinked structure can be converted to one-dimensional and two-dimensional structures commonly seen for organic polymers. Subsequently, addition of ionic liquid allows “plasticization” of silicate glass, and results in further reduction in bond strength and Tg; materials behave as polymers. Results show that Tg of modified silicate glass can be decreased from 410 C to 155 C by addition of ionic liquid; i.e., by plasticization with ionic liquid. The properties and reaction mechanism of synthesized inorganic polymers are investigated by various characterization methods, such as DSC, FTIR, XRD, XPS, SEM, and TEM, in addition to mechanical testing.
Subject (authority = RUETD)
Topic
Chemical and Biochemical Engineering
Subject (authority = ETD-LCSH)
Topic
Inorganic polymers
RelatedItem (type = host)
TitleInfo
Title
Rutgers University Electronic Theses and Dissertations
Identifier (type = RULIB)
ETD
Identifier
ETD_9194
PhysicalDescription
Form (authority = gmd)
electronic resource
InternetMediaType
application/pdf
InternetMediaType
text/xml
Extent
1 online resource (102 pages) : illustrations
Note (type = degree)
Ph.D.
Note (type = bibliography)
Includes bibliographical references
Note (type = statement of responsibility)
by Monika Kazancioglu
RelatedItem (type = host)
TitleInfo
Title
School of Graduate Studies Electronic Theses and Dissertations
Identifier (type = local)
rucore10001600001
Location
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NjNbRU
Identifier (type = doi)
doi:10.7282/t3-spzx-er68
Genre (authority = ExL-Esploro)
ETD doctoral
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Rights

RightsDeclaration (ID = rulibRdec0006)
The author owns the copyright to this work.
RightsHolder (type = personal)
Name
FamilyName
Kazancioglu
GivenName
Monika
Role
Copyright Holder
RightsEvent
Type
Permission or license
DateTime (encoding = w3cdtf); (qualifier = exact); (point = start)
2018-09-14 10:27:34
AssociatedEntity
Name
Monika Kazancioglu
Role
Copyright holder
Affiliation
Rutgers University. School of Graduate Studies
AssociatedObject
Type
License
Name
Author Agreement License
Detail
I hereby grant to the Rutgers University Libraries and to my school the non-exclusive right to archive, reproduce and distribute my thesis or dissertation, in whole or in part, and/or my abstract, in whole or in part, in and from an electronic format, subject to the release date subsequently stipulated in this submittal form and approved by my school. I represent and stipulate that the thesis or dissertation and its abstract are my original work, that they do not infringe or violate any rights of others, and that I make these grants as the sole owner of the rights to my thesis or dissertation and its abstract. I represent that I have obtained written permissions, when necessary, from the owner(s) of each third party copyrighted matter to be included in my thesis or dissertation and will supply copies of such upon request by my school. I acknowledge that RU ETD and my school will not distribute my thesis or dissertation or its abstract if, in their reasonable judgment, they believe all such rights have not been secured. I acknowledge that I retain ownership rights to the copyright of my work. I also retain the right to use all or part of this thesis or dissertation in future works, such as articles or books.
RightsEvent
Type
Embargo
DateTime (encoding = w3cdtf); (qualifier = exact); (point = start)
2018-10-31
DateTime (encoding = w3cdtf); (qualifier = exact); (point = end)
2020-10-30
Detail
Access to this PDF has been restricted at the author's request. It will be publicly available after October 30th, 2020.
Copyright
Status
Copyright protected
Availability
Status
Open
Reason
Permission or license
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Technical

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DateCreated (point = end); (encoding = w3cdtf); (qualifier = exact)
2018-09-09T14:35:30
DateCreated (point = end); (encoding = w3cdtf); (qualifier = exact)
2018-09-09T14:35:30
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