Home
Resource
Ultra-stable zirconium-based cationic metal-organic frameworks for perrhenate removal from waste water
PDF
PDF format is widely accepted and good for printing.
Plug-in required
PDF-1(2.58 MB)
Citation & Export
View Usage Statistics
Staff View

Citation & Export
Hide

Simple citation

Zhang, Guoyu. Ultra-stable zirconium-based cationic metal-organic frameworks for perrhenate removal from waste water. Retrieved from https://doi.org/doi:10.7282/t3-7eth-r890

Export

Click here for information about Citation Management Tools at Rutgers.

Statistics
Hide

Description

TitleUltra-stable zirconium-based cationic metal-organic frameworks for perrhenate removal from waste water
NameZhang, Guoyu (author); Li, Jing (chair); Goldman, Alan (internal member); Zhang, Jianyuan (internal member); Rutgers University; School of Graduate Studies
Date Created2019
Other Date2019-10 (degree)
SubjectCationic metal-organic framework, Chemistry and Chemical Biology, Water treatment plant residuals, Hazardous waste site remediation
Extent1 online resource (viii, 41 pages) : illustrations
DescriptionRemoving a large abundant of radioactive 99TcO4- anion from nuclear waste water in Hanford Site is still a very difficult problem remaining to be solved. Functional materials with high stability, anion-exchange capacity, selectivity, and recyclability are eagerly awaited to solve this difficulty. Herein, we report two stable cationic metal-organic frameworks — Zr-tcbp-Me and Zr-tcpp-Me which were synthesized through the tetracarboxylic linkers bonding with zirconium cluster and post-synthetic modification (N-methylation). Both MOFs can retain their crystallinities under harsh condition and have high removability and selectivity towards ReO4- anion, a non-radioactive surrogate of 99TcO4- to be studied. This work represents the highest stability towards the acidic condition that cationic MOFs are used to remove perrhenate from waste water.
NoteM.S.
NoteIncludes bibliographical references
Genretheses, ETD graduate
Persistent URLhttps://doi.org/doi:10.7282/t3-7eth-r890
LanguageEnglish
CollectionSchool of Graduate Studies Electronic Theses and Dissertations
Organization NameRutgers, The State University of New Jersey
RightsThe author owns the copyright to this work.
Version 8.5.5
Rutgers University Libraries - Copyright ©2024