RUcore: Rutgers University Community Repository
Upscale synthesis of symmetrical and unsymmetrical monomers towards bridge triflouromethylated poly (p-phenylenevinylene) and theoretical NMR studies
Descriptive
TypeOfResource
Text
TitleInfo
(ID = T-1)
Title
Upscale synthesis of symmetrical and unsymmetrical monomers towards bridge triflouromethylated poly (p-phenylenevinylene) and theoretical NMR studies
Identifier
ETD_1019
Identifier
(type = hdl)
http://hdl.rutgers.edu/1782.2/rucore10005600001.ETD.000051324
Language
LanguageTerm
(authority = ISO639-2);
(type = code)
eng
Genre
(authority = marcgt)
theses
Subject
(ID = SBJ-1);
(authority = RUETD)
Topic
Chemistry
Subject
(ID = SBJ-1);
(authority = ETD-LCSH)
Topic
Monomers
Subject
(ID = SBJ-1);
(authority = ETD-LCSH)
Topic
Polymers
Subject
(ID = SBJ-1);
(authority = ETD-LCSH)
Topic
Polymerization
Subject
(ID = SBJ-1);
(authority = ETD-LCSH)
Topic
Nucleophilic reactions
Abstract
The objective of this research is to up scale the synthesis of previously reported symmetrical and unsymmetrical trifluoromethylated monomers in sufficiently high amounts for the synthesis and characterization of bridge substituted poly (p-phenylene) vinylene polymers. Theoretical NMR calculations are also made to differentiate between diastereomers produced during synthesis. The preliminary polymerization reactions yielded optimistic results but insufficient material was used for proper polymerization, characterization, and isolation. The monomers prepared are shown in Table 1.
PhysicalDescription
Form
(authority = marcform)
electronic
Extent
viii, 64 p. : ill. (some col.)
InternetMediaType
application/pdf
InternetMediaType
text/xml
Note
Supplementary File: Table 2: Common p-type dopants for Polyacetylene4
Note
Supplementary File: Table 3: Common n-type dopants for Polyacetylene4
Note
(type = degree)
M.S.
Note
(type = bibliography)
Includes bibliographical references (p. 63-64).
Note
(type = statement of responsibility)
by Jean Pierre Pinto
Name
(ID = NAME-1);
(type = personal)
NamePart
(type = family)
Pinto
NamePart
(type = given)
Jean Pierre
Role
RoleTerm
(authority = RULIB);
(type = )
author
DisplayForm
Jean Pierre Pinto
Name
(ID = NAME-2);
(type = personal)
NamePart
(type = family)
Burke
NamePart
(type = given)
Luke A.
Role
RoleTerm
(authority = RULIB);
(type = )
chair
Affiliation
Advisory Committee
DisplayForm
Luke A. Burke
Name
(ID = NAME-3);
(type = personal)
NamePart
(type = family)
Roche
NamePart
(type = given)
Alex J.
Role
RoleTerm
(authority = RULIB);
(type = )
internal member
Affiliation
Advisory Committee
DisplayForm
Alex J. Roche
Name
(ID = NAME-4);
(type = personal)
NamePart
(type = family)
Arbuckle-Keil
NamePart
(type = given)
Georgia A.
Role
RoleTerm
(authority = RULIB);
(type = )
internal member
Affiliation
Advisory Committee
DisplayForm
Georgia A. Arbuckle-Keil
Name
(ID = NAME-1);
(type = corporate)
NamePart
Rutgers University
Role
RoleTerm
(authority = RULIB);
(type = )
degree grantor
Name
(ID = NAME-2);
(type = corporate)
NamePart
Camden Graduate School
Role
RoleTerm
(authority = RULIB);
(type = )
school
OriginInfo
DateCreated
(point = );
(qualifier = exact)
2008
DateOther
(qualifier = exact);
(type = degree)
2008-05
Place
PlaceTerm
(type = code)
xx
Location
PhysicalLocation
(authority = marcorg);
(type = code)
NjNbRU
RelatedItem
(type = host)
TitleInfo
Title
Rutgers University Electronic Theses and Dissertations
Identifier
(type = RULIB)
ETD
RelatedItem
(type = host)
TitleInfo
Title
Camden Graduate School Electronic Theses and Dissertations
Identifier
(type = local)
rucore10005600001
Location
PhysicalLocation
(authority = marcorg);
(displayLabel = Rutgers, The State University of New Jersey)
NjNbRU
Identifier
(type = doi)
doi:10.7282/T36973S8
Genre
(authority = ExL-Esploro)
ETD graduate
Back to the top
Rights
RightsDeclaration
(AUTHORITY = GS);
(ID = rulibRdec0006)
The author owns the copyright to this work.
Copyright
Status
Copyright protected
Availability
Status
Open
RightsEvent
(AUTHORITY = rulib);
(ID = 1)
Type
Permission or license
Detail
Non-exclusive ETD license
AssociatedObject
(AUTHORITY = rulib);
(ID = 1)
Type
License
Name
Author Agreement License
Detail
I hereby grant to the Rutgers University Libraries and to my school the non-exclusive right to archive, reproduce and distribute my thesis or dissertation, in whole or in part, and/or my abstract, in whole or in part, in and from an electronic format, subject to the release date subsequently stipulated in this submittal form and approved by my school. I represent and stipulate that the thesis or dissertation and its abstract are my original work, that they do not infringe or violate any rights of others, and that I make these grants as the sole owner of the rights to my thesis or dissertation and its abstract. I represent that I have obtained written permissions, when necessary, from the owner(s) of each third party copyrighted matter to be included in my thesis or dissertation and will supply copies of such upon request by my school. I acknowledge that RU ETD and my school will not distribute my thesis or dissertation or its abstract if, in their reasonable judgment, they believe all such rights have not been secured. I acknowledge that I retain ownership rights to the copyright of my work. I also retain the right to use all or part of this thesis or dissertation in future works, such as articles or books.
Back to the top
Technical
ContentModel
ETD
MimeType
(TYPE = file)
application/pdf
MimeType
(TYPE = container)
application/x-tar
FileSize
(UNIT = bytes)
2908160
Checksum
(METHOD = SHA1)
23cfc112b31818f782807e59bceaee292760073c
Back to the top
Statistical Profile