Xu, Xianghan. Unconventional ferroelectricity, quantum magnetism, and multiferroicity of single-crystalline quantum materials. Retrieved from https://doi.org/doi:10.7282/t3-02hw-9s64
DescriptionIn the first chapter, single crystal growth techniques, ferroic orders, and magnetoelectricity are introduced. In the second chapter, the phenomenological theory of ferroelectric transition is introduced. Unconventional ferroelectrics examples Sr₃Sn₂O₇, a hybrid improper ferroelectrics with high tunability, and HfO₂:Y bulk crystals showing metastable ferroelectric phase are demonstrated to show how their single-crystalline materials help to improve the ferroelectric performance and understand the physics. The third chapter shows the multiple ferroic orders, novel magnetic ground state, and toroidal magnetoelectricity in a chiral magnet BaCoSiO₄, in which the single crystal unambiguously reveals the anisotropic magnetism and magnetoelectric tensor. Beyond the experimental demonstration of BaCoSiO₄, a new concept- magnetic chirality is proposed and discussed. In the last chapter, recently proposed unconventional crystal growth techniques are reviewed, and the growth and property of a chiral superconductor Mo₃Al₂C are introduced as a successful example of the alumina tube sealing technique. This thesis highlights the laser floating zone as a breakthrough growth technique leading to unique single-crystalline quantum materials which have not been studied before.