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Unambiguous full multinuclear NMR assignment of 4-amino-1,1,2,2,9,9,10,10-octafluoro[2.2]paracycylophane & NMR differentiation of its enantiomers, and related compounds
Descriptive
TitleInfo
Title
Unambiguous full multinuclear NMR assignment of 4-amino-1,1,2,2,9,9,10,10-octafluoro[2.2]paracycylophane & NMR differentiation of its enantiomers, and related compounds
Name
(type = personal)
NamePart
(type = family)
Rabinowitz
NamePart
(type = given)
Sheryl
NamePart
(type = date)
1969-
DisplayForm
Sheryl Rabinowitz
Role
RoleTerm
(authority = RULIB)
author
Name
(type = personal)
NamePart
(type = family)
Roche
NamePart
(type = given)
Alex J
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Alex J Roche
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Advisory Committee
Role
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chair
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Kumi
NamePart
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George A
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George A Kumi
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Advisory Committee
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internal member
Name
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Canturk
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Belgin
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Belgin Canturk
Affiliation
Advisory Committee
Role
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outside member
Name
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NamePart
Rutgers University
Role
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degree grantor
Name
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NamePart
Camden Graduate School
Role
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school
TypeOfResource
Text
Genre
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theses
OriginInfo
DateCreated
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2013
DateOther
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(type = degree)
2013-01
Place
PlaceTerm
(type = code)
xx
Language
LanguageTerm
(authority = ISO639-2b);
(type = code)
eng
Abstract
(type = abstract)
For the first time the full multinuclear ¹H, ¹³C, and ¹⁹F assignments were established for 4-amino-1,1,2,2,9,9,10,10-octafluoro[2.2]paracyclophane (OFP-NH2). These were achieved by using a combination of 1D, COSY, and HETCOR NMR techniques. The assignments were later confirmed by nOe experiments. The interaction of OFP-NH₂ with different chiral shift reagents was explored, and it was shown that it is possible to clearly detect both enantiomers of the planar chiral OFP-NH₂ (in both the ¹H and ¹⁹F NMR). This method of chiral discrimination was also shown to be applicable to other similar chiral OFP derivatives.
Subject
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Topic
Chemistry
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Title
Rutgers University Electronic Theses and Dissertations
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ETD_4513
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electronic resource
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Note
Supplementary File: Figure 2.4 AB Pattern Diagram p16
Extent
xii, 127 p. : ill.
Note
(type = degree)
M.S.
Note
(type = bibliography)
Includes bibliographical references
Note
(type = statement of responsibility)
by Sheryl Rabinowitz
Subject
(authority = ETD-LCSH)
Topic
Nuclear magnetic resonance
Subject
(authority = ETD-LCSH)
Topic
Chirality
Subject
(authority = ETD-LCSH)
Topic
Cyclophanes
Identifier
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http://hdl.rutgers.edu/1782.1/rucore10005600001.ETD.000067579
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Title
Camden Graduate School Electronic Theses and Dissertations
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rucore10005600001
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NjNbRU
Identifier
(type = doi)
doi:10.7282/T3B56HGP
Genre
(authority = ExL-Esploro)
ETD graduate
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Rights
RightsDeclaration
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The author owns the copyright to this work.
RightsHolder
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Name
FamilyName
Rabinowitz
GivenName
Sheryl
Role
Copyright Holder
RightsEvent
Type
Permission or license
DateTime
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(qualifier = exact);
(point = start)
2013-01-27 16:29:51
AssociatedEntity
Name
Sheryl Rabinowitz
Role
Copyright holder
Affiliation
Rutgers University. Camden Graduate School
AssociatedObject
Type
License
Name
Author Agreement License
Detail
I hereby grant to the Rutgers University Libraries and to my school the non-exclusive right to archive, reproduce and distribute my thesis or dissertation, in whole or in part, and/or my abstract, in whole or in part, in and from an electronic format, subject to the release date subsequently stipulated in this submittal form and approved by my school. I represent and stipulate that the thesis or dissertation and its abstract are my original work, that they do not infringe or violate any rights of others, and that I make these grants as the sole owner of the rights to my thesis or dissertation and its abstract. I represent that I have obtained written permissions, when necessary, from the owner(s) of each third party copyrighted matter to be included in my thesis or dissertation and will supply copies of such upon request by my school. I acknowledge that RU ETD and my school will not distribute my thesis or dissertation or its abstract if, in their reasonable judgment, they believe all such rights have not been secured. I acknowledge that I retain ownership rights to the copyright of my work. I also retain the right to use all or part of this thesis or dissertation in future works, such as articles or books.
Copyright
Status
Copyright protected
Availability
Status
Open
Reason
Permission or license
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Technical
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ETD
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windows xp
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ETD
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ETD
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